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Natural Science Forum / Physics / Particle Physics / May 2008



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Inaccurate QM Prediction for Hydrogen

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Steve Bell - 21 Apr 2008 18:47 GMT
Every few years, I return to these newsgroup lists to try and resolve an
issue I have noticed for years. It is this. It appears to me that QM
(specifically QED) makes an inaccurate prediction for the ground state
binding energy of hydrogen, one of the most fundamental values in the atomic
physics. Since the hydrogen atom is the most simplest of atoms, and the
ground state is the most simplest of its energy levels, and since QED claims
to be extremely accurate in its predictions, one would think QED's
prediction would agree very well with the observed value.  It appears to me
that it does not.

This time around, I have found numbers on the net that were not generated by
myself, and I will present these numbers, which appear to substantiate my
claim. I want to stress, I completely understand that such a contention, on
face value, would appear to be highly unlikely. It is reasonable for anyone
to think that if I were correct, such an error would have been seen many
years ago by many people, and we would all know about it. But it does not
appear to me that QED physicists have noticed this error, and that confuses
me significantly, because it seems so apparent. I vow, though, that if
someone can show me the error of my ways, I will accept I am wrong, and quit
trying to convince the QM community. I will apologize profusely for wasting
everybody's time.

I have always employed the scientific method here, that is, establish what
the observed ground state binding energy is, then look at various
theoretical predictions, and decide which one appears the most correct. So,
here we go. The first thing to do is to establish what everyone agrees is
the best, most accurate experimentally derived value for hydrogen's ground
state binding energy. Since there is a one-to-one correspondence between the
Rydberg constant for hydrogen and its ground state binding energy, a good
way to begin is to agree on what is the best observed value for hydrogen's
Rydberg constant. I have found a link, at
http://www.lancs.ac.uk/users/spc/teaching/py301/phys301.htm. This link
provides a value for R_H where it is stated (Part 5, page 9) the value is
derived "from expt (line spectra)." The value is 1.0967759 x 10^-7 m^-1. Can
we all agree this is an accurate observed value of R_H? If you can find a
reference that provides a significantly different value, I would be very
surprised, because I have references that trace back essentially this same
value for the past 30 years or so.

Steve Bell
Eric Gisse - 22 Apr 2008 02:41 GMT
[snip]

Where is the inaccurate prediction?
Steve Bell - 22 Apr 2008 04:19 GMT
Hi Eric,

Thank you for taking an interest. I hope others do too. I'll provide a link
to a paper that provides a QED prediction, but only after folks agree on the
observed value. In the past, I have provided my own predictions, but this
time, I do not want there to be any issue of me not having done that
correctly.

As a hint of the final outcome I hope to show, if you looked at the link I
gave for the observed value (the PowerPoint slides), note how the author
stated "fantastically good agreement between theory and expt!". I would like
for you to consider the nature of the theory that provided this
"fantastically good agreement."

Steve

On Apr 21, 9:47 am, "Steve Bell" <sb...@starband.net> wrote:
[snip]

Where is the inaccurate prediction?
Eric Gisse - 22 Apr 2008 06:21 GMT
> Hi Eric,
>
[quoted text clipped - 9 lines]
> for you to consider the nature of the theory that provided this
> "fantastically good agreement."

If you can't do better than power point slides for an undergrad QM
class, then there really isn't much point in discussing this. Oh, and
don't f.cking top post.

[snip]
Steve Bell - 22 Apr 2008 07:41 GMT
On Apr 21, 7:19 pm, "Steve Bell" <sb...@starband.net> wrote:
> Hi Eric,
>
[quoted text clipped - 9 lines]
> for you to consider the nature of the theory that provided this
> "fantastically good agreement."

If you can't do better than power point slides for an undergrad QM
class, then there really isn't much point in discussing this. Oh, and
don't f.cking top post.

[snip]

Hi Eric,

Thanks for responding. If you have some doubts about the observed value
given in the PPT files, here is a reference of a well respected QM text
"Quantum Physics of Atoms, Molecules, Solids, Nuclei, and Particles," by R.
Eisberg and R. Resnick. I have the 2nd edition, and on p. 98, these authors
provide an R_H value "from recent spectroscopic data" of R_H = 10967757.6
m^1. This number is only different by about 1.4 m^-1 from the number
provided in the PPT slides. The reason I provided the link to the PPT slides
is that perhaps not everyone has the Eisberg and Resnick text, and I didn't
want to simply post a number on my own. I didn't want there to be any doubt
about the numbers, both observed and predicted. I give you my word, I will
not post any numbers that I myself have "crunched" in any way. The Eisberg
and Resnick 1st edition looks to have been published in 1974, and I think
the 1st edition also listed a similar value. I'd have to look up in my past
notes, but I remember finding a well respected reference that goes back to
the 1950s with essentially the same number. It looks like this observed
value has been around for > 50 years with little change. This suggests to me
that the value in the PPT file is an acceptably accurate value for an
experimentally determined R_H. Would you agree? If you don't agree, I would
very much appreciate it you would try and track down a value that you think
is accurate, and post it here.

Thanks,
Steve
Eric Gisse - 22 Apr 2008 08:15 GMT
> On Apr 21, 7:19 pm, "Steve Bell" <sb...@starband.net> wrote:
>
[quoted text clipped - 46 lines]
> Thanks,
> Steve

The Rydberg constant isn't empirically determined to my knowledge - it
is a composition of a half dozen fundamental constants.
Steve Bell - 22 Apr 2008 16:26 GMT
On Apr 21, 10:41 pm, "Steve Bell" <sb...@starband.net> wrote:
> "Eric Gisse" <jowr...@gmail.com> wrote in message
>
[quoted text clipped - 48 lines]
> Thanks,
> Steve

The Rydberg constant isn't empirically determined to my knowledge - it
is a composition of a half dozen fundamental constants.

Hi Eric,

Thanks for responding. I am wondering, then, what the words "from expt (line
spectra)" and "from recent spectroscopic data" mean.

Steve
Eric Gisse - 22 Apr 2008 17:30 GMT
> On Apr 21, 10:41 pm, "Steve Bell" <sb...@starband.net> wrote:
>
[quoted text clipped - 71 lines]
>
> Steve

Think about it. How much energy does it take to fully ionize Hydrogen,
and how does it relate to spectra and the Rydberg constant?
Steve Bell - 22 Apr 2008 18:01 GMT
On Apr 22, 7:26 am, "Steve Bell" <sb...@starband.net> wrote:
> "Eric Gisse" <jowr...@gmail.com> wrote in message
>
[quoted text clipped - 74 lines]
>
> Steve

Think about it. How much energy does it take to fully ionize Hydrogen,
and how does it relate to spectra and the Rydberg constant?

Hi Eric,

I think I understand that. I was hoping to ask a more fundamental question.
It appears to me, these "from expt (line spectra)" and "from recent
spectroscopic data" seem to imply these values have nothing at all to do
with any theory. While I was "hiding," I looked into how the spectroscopic
data are used. Of course, the only thing that can be observed are energy
level differences, and some techniques simply fit a generic polynomial to
the data and interpolate a value for R_H. These generic polynomials have
nothing to do with any theory. Some techniques fit the Rydberg equation and
interpolate, but the Rydberg equation is empirical itself, and not really
based on any theory, at least originally. I assume the observed frequencies
associated with the energy level differences are also "unbiased." They only
present what hydrogen "naturally" shows to us. Btw, I mentioned this
"observed value" has been around for 50 years,  or maybe even longer. It
would make sense this would happen, if indeed the spectroscopic machinery of
even 50 years ago was good enough to fairly well pin down an observed R_H.
Certainly, the spectroscopic machinery of today is much better, but
apparently it was pretty good a significant while back, and the observed
value of R_H has not changed much. Hydrogen certainly has not changed in the
last 50 years, or even in the last 13.7 billion years for that matter!

I started this thread saying that I will fully admit I am wrong if someone
can show me how these supposedly correct applications of the scientific
method are indeed not that. The fact though, that the observed value has not
changed much in the past 50 years, strongly implies the value of 10967759
m^-1 is a pretty good unbiased observed number for R_H. If so, the
inescapable conclusion (imo) is that QED has a problem.

Steve
Autymn D. C. - 30 Apr 2008 12:00 GMT
> On Apr 22, 7:26 am, "Steve Bell" <sb...@starband.net> wrote:
>
[quoted text clipped - 112 lines]
> value of R_H has not changed much. Hydrogen certainly has not changed in the
> last 50 years, or even in the last 13.7 billion years for that matter!

Of course it has; everything has.  Even fundamental "constants" hav
shifted in the last five years: http://google.com/groups?q=fundamental-constants+Autymn.
Autymn D. C. - 30 Apr 2008 12:02 GMT
> On Apr 22, 7:26 am, "Steve Bell" <sb...@starband.net> wrote:
>
[quoted text clipped - 112 lines]
> value of R_H has not changed much. Hydrogen certainly has not changed in the
> last 50 years, or even in the last 13.7 billion years for that matter!

Of course it has; everything has.  Even fundamental constants hav
shifted: http://google.com/groups?q=Autymn+PDG+sigma.
Jerry - 22 Apr 2008 12:18 GMT
> Every few years, I return to these newsgroup lists to try and resolve an
> issue I have noticed for years. It is this. It appears to me that QM
[quoted text clipped - 27 lines]
> way to begin is to agree on what is the best observed value for hydrogen's
> Rydberg constant. I have found a link, at
http://www.lancs.ac.uk/users/spc/teaching/py301/phys301.htm. This link
> provides a value for R_H where it is stated (Part 5, page 9) the value is
> derived "from expt (line spectra)." The value is 1.0967759 x 10^-7 m^-1. Can
> we all agree this is an accurate observed value of R_H? If you can find a
> reference that provides a significantly different value, I would be very
> surprised, because I have references that trace back essentially this same
> value for the past 30 years or so.

Big Freaking Deal.

You present Powerpoint slides giving a non-relativistic QM
treatment of the computation, followed by a reference to an
undergraduate textbook written for an introductory QM class,
and conclude that QED is wrong because the naive computation
of the Rydberg constant only gives four significant figures?

Crawl back into your hole until you learn QED.

Jerry
Jerry - 22 Apr 2008 12:39 GMT
> > Every few years, I return to these newsgroup lists to try and resolve an
> > issue I have noticed for years. It is this. It appears to me that QM
[quoted text clipped - 44 lines]
> and conclude that QED is wrong because the naive computation
> of the Rydberg constant only gives four significant figures?

Sorry. I was looking at R_infinity, not R_H
I should have written that the naive computation gives EIGHT
significant figures.

> Crawl back into your hole until you learn QED.

Jerry
Eric Gisse - 22 Apr 2008 13:26 GMT
> > > Every few years, I return to these newsgroup lists to try and resolve an
> > > issue I have noticed for years. It is this. It appears to me that QM
[quoted text clipped - 48 lines]
> I should have written that the naive computation gives EIGHT
> significant figures.

No, it can't. Nonrelativistic QM [which is the baseline for the class
in question, I'm not installing something to view the powerpoint
slides] is only accurate to order ~ alpha.

Regarding the Hydrogen spectra...

Regular ol' nonrelativistic QM gets you most of the way there.
Everything else can be interpreted as a higher order correction to the
Schroedinger equation - unless you solve the Dirac equation proper.

Baseline QM gets you ~ alpha accuracy. Accounting for relativistic
effects and electron spin coupling to the magnetic field of the proton
gets you another factor of alpha. Including electron spin to proton
spin coupling gets you alpha^3. QED corrections [Lamb shift] are dead
last - alpha^4. That'll get you the eight figures you want, but it is
not a naive computation in any sense - I can do all of those except
the Lamb shift corrections, and they consume paper.

I'd like to believe the ordering and _order_ are correct, except my
main reference for all this is out on loan [and has been for most of a
year now. time to get it back] so I can't check easily.

I'm just not getting the point of this thread - he won't say what the
prediction is, or disagree with me when I say the Rydberg constant is
just a bunch of constants thrown together that doesn't have a good
empirical measurement anyway, or even say how the prediction is
inaccurate.

> > Crawl back into your hole until you learn QED.
>
> Jerry
Jerry - 22 Apr 2008 14:23 GMT
> I'm just not getting the point of this thread - he won't say what the
> prediction is, or disagree with me when I say the Rydberg constant is
> just a bunch of constants thrown together that doesn't have a good
> empirical measurement anyway, or even say how the prediction is
> inaccurate.

I searched for "Steve Bell" on these newsgroups. Look for
his dialogs with Bilge and some of the other old-timers who
unfortunately aren't still around.

His point seems to be that the non-relativistic QM calculation
fails to give a number that agrees with computations of the
Rydberg constant based on the best available empirical data.
The discrepancy amounts to thousands of standard deviations.

Bilge gets exasperated, provides links to current material,
then Steve goes into hiding and starts up again making the
point that the non-relativistic QM calculation fails to give
a number that agrees with computations of the Rydberg
constant based on the best available empirical data. The
discrepancy amounts to thousands of standard deviations.

Repeat ad nauseam.

Jerry
Eric Gisse - 22 Apr 2008 14:49 GMT
> > I'm just not getting the point of this thread - he won't say what the
> > prediction is, or disagree with me when I say the Rydberg constant is
[quoted text clipped - 5 lines]
> his dialogs with Bilge and some of the other old-timers who
> unfortunately aren't still around.

Holy sh.t - same title and arguments too!

At least I can claim I have learned something in six years...

The 2002 thread wasn't terribly interesting - Bilge repeated stuff I
already knew. The 2003 thread was more interesting - Bob had some nice
background to fill in. Then Bilge had more interesting things to say -
worth reading.

http://groups.google.com/group/sci.physics.particle/browse_frm/thread/ec48a0ed32
fe09ad


> His point seems to be that the non-relativistic QM calculation
> fails to give a number that agrees with computations of the
> Rydberg constant based on the best available empirical data.
> The discrepancy amounts to thousands of standard deviations.

Then everyone agrees with him, and wonders what the problem is.
Classical anything is only an approximation - why is this such a
surprise to folks here?

> Bilge gets exasperated, provides links to current material,
> then Steve goes into hiding and starts up again making the
[quoted text clipped - 6 lines]
>
> Jerry
Steve Bell - 22 Apr 2008 16:59 GMT
On Apr 22, 7:26 am, Eric Gisse <jowr...@gmail.com> wrote:

> I'm just not getting the point of this thread - he won't say what the
> prediction is, or disagree with me when I say the Rydberg constant is
> just a bunch of constants thrown together that doesn't have a good
> empirical measurement anyway, or even say how the prediction is
> inaccurate.

I searched for "Steve Bell" on these newsgroups. Look for
his dialogs with Bilge and some of the other old-timers who
unfortunately aren't still around.

His point seems to be that the non-relativistic QM calculation
fails to give a number that agrees with computations of the
Rydberg constant based on the best available empirical data.
The discrepancy amounts to thousands of standard deviations.

Bilge gets exasperated, provides links to current material,
then Steve goes into hiding and starts up again making the
point that the non-relativistic QM calculation fails to give
a number that agrees with computations of the Rydberg
constant based on the best available empirical data. The
discrepancy amounts to thousands of standard deviations.

Repeat ad nauseam.

Jerry

Hi Jerry,

Thanks for participating. If I am interpreting you correctly, that was not
quite what I thought in the past, namely, I did not think "His point seems
to be that the non-relativistic QM calculation fails to give a number that
agrees with computations of the Rydberg constant based on the best available
empirical data. The discrepancy amounts to thousands of standard
deviations." My point was that the QED prediction does not agree with what
very apparently is portrayed in the literature as an unbiased, not
influenced by theory value, i.e., a spectroscopic-data-empirical value of
R_H. After all, hydrogen must naturally posses what we would call "its true
Rydberg constant value." and that is the definite implication in these
references. The presentations in these references are clearly trying to
employ a correct scientific method where theory is compared to observations.
I want and hope to so the same. If you did examine the threads in the past,
there were a least a couple of people who appreciated what I had to say.
Perhaps that will not happen here again, but I'm going to try anyway.

Thanks,
Steve
Ken S. Tucker - 22 Apr 2008 17:31 GMT
Hi Steve, nice to see you post.

> "Jerry" <Cephalobus_alie...@comcast.net> wrote in message
...
> Hi Jerry,
> Thanks for participating. If I am interpreting you correctly, that was not
[quoted text clipped - 12 lines]
> there were a least a couple of people who appreciated what I had to say.
> Perhaps that will not happen here again, but I'm going to try anyway.

IIRC,(foggy from years ago), you decided
the Bohr Correspondence Principle, was
the more accurate of the Rydberg calc.
Anyway, I'll lurk the discussion, and
add what I can.

> Thanks,
> Steve

Welcome, thanks
Ken S. Tucker
Steve Bell - 22 Apr 2008 18:20 GMT
> Hi Steve, nice to see you post.
>
[quoted text clipped - 28 lines]
> Welcome, thanks
> Ken S. Tucker

Hi Ken,

Thanks for participating. I don't know if I'll say it's good to be back, but
I'm a bit older now and hopefully wiser. I am not going to present any
numbers I myself "crunched," maybe that will impress upon some I'm trying to
be honest here. I would not exactly say it was the Bohr Correspond
Principle, but the Bohr energy equation itself which provided a more
accurate R_H prediction. This time around, I'm not even going to mention
Bohr (not at first, anyway). Since the non-relativistic Schroedinger
equation is identical to Bohr's equation, I'll just say that it's the
non-relativistic Schoe. theory that appears most accurate. This is what I
had hoped some would see by my asking to "please consider the nature of the
theory that provides this 'fanatically good agreement between theory and
expt!' as the PPT slides point out.

Steve
Ken S. Tucker - 22 Apr 2008 21:46 GMT
To Steve.

> > Hi Steve, nice to see you post.
>
[quoted text clipped - 53 lines]
> expt!' as the PPT slides point out.
> Steve

You should lay your cards out.
Myself I'm trying to figure out if I should
apply relativistic corrections within the
structure of an electron!
I occasionally post on that.
Ken S. Tucker
Steve Bell - 22 Apr 2008 22:08 GMT
> To Steve.
>
> > "Ken S. Tucker" <dynam...@vianet.on.ca> wrote in messagenews:62dd766a-24df-417c-902c-a18bdad7c652@e67g2000hsa.googlegroups.co
m...

> > > Hi Steve, nice to see you post.
> >
[quoted text clipped - 60 lines]
> I occasionally post on that.
> Ken S. Tucker

Hi Ken,

Yes, I've done so in another post. If an electron does have internal
structure, which like you, I think it does, then I would say you should
apply relativistic corrections. Relativistic effects have to be present,
assuming relativity theory is physically correct, which I certainly think it
is.

Steve
Ken S. Tucker - 22 Apr 2008 22:38 GMT
> > > "Ken S. Tucker" <dynam...@vianet.on.ca> wrote in
>
[quoted text clipped - 89 lines]
>
> Steve

Well Steve, A few fella's got together and set up
a new group, "Sci.Physics.Foundations" that have
some highly knowledgeable posters, and is moderated
for good reasons, but they even let me post there
from time to time, so you're a shoe in!
Check it out.
Ken S. Tucker

BTW: I think you're right, a relativistic correction
is necessary.
Steve Bell - 22 Apr 2008 23:12 GMT
...> To Steve.

> > > > "Ken S. Tucker" <dynam...@vianet.on.ca> wrote in

messagenews:62dd766a-24df-417c-902c-a18bdad7c652@e67g2000hsa.googlegroups.co
> > m...
> >
[quoted text clipped - 97 lines]
> BTW: I think you're right, a relativistic correction
> is necessary.

Hi Ken,

I looked on my ISP's newsgroups, but I didn't find it. Or I don't how to
locate it. How do I do that? Are you sure they would allow discussions of
these controversial ideas? It sure would be nice to get off of
sci.physics.relativity. Btw, was it you who thought an electron coasts on a
geodesic? If so, I completely agree, with all of the differential-geometry
implications that the word "geodesic" conveys. You know, I actually
sometimes hope I am wrong here, about this hydrogen stuff. I'm getting very
tired of fighting the fight, and it would be nice to get a clear explanation
of the error in my thinking. Devastating to my ego, but nice none the less.

Steve
Ken S. Tucker - 22 Apr 2008 23:23 GMT
> "Ken S. Tucker" <dynam...@vianet.on.ca> wrote in
...
> > Well Steve, A few fella's got together and set up
> > a new group, "Sci.Physics.Foundations" that have
[quoted text clipped - 19 lines]
> of the error in my thinking. Devastating to my ego, but nice none the less.
> Steve

Here's what I have,
sci . physics . foundations
Maybe someone else can get your there.
Also use sci.phy.research.
Ken
FrediFizzx - 23 Apr 2008 07:37 GMT
> Hi Ken,
>
[quoted text clipped - 14 lines]
> of the error in my thinking. Devastating to my ego, but nice none the
> less.

Hi Steve,

If your ISP doesn't carry sci.physics.foundations yet, you can access
via googlegroups or Killfile.org

http://groups.google.com/group/sci.physics.foundations/topics?hl=en

http://news.killfile.org/index.cgi?group=sci.physics.foundations

They are not quite as good as going thru a proper news server and
newsreader but works OK.

If you can give me an email address for how to contact your ISP's news
server sysop, I will send them an email requesting that they add SPF to
their news server.  And/or you can ask them to add it yourself.  Doesn't
always work but does sometimes.  You need to tell them to set it up as a
moderated Usenet group.

We generally have a light moderation policy and allow most all content
related to physics as long as it is clearly not contrary to experimental
evidence.  Speculative content is allowed as well as philosophical
content related to physics.  Most important is that we do expect posters
to be polite unlike some that have responded to you here.  We do stop
threads that become highly repetitive.  If interested, the charter for
sci.physics.foundations is here;

http://readystump.algebra.com/~spf/

Best,

Fred Diether
Co-moderator  sci.physics.foundations
FrediFizzx - 23 Apr 2008 07:50 GMT
>> Hi Ken,
>>
[quoted text clipped - 47 lines]
> Fred Diether
> Co-moderator  sci.physics.foundations

P.S.  I forgot to mention that we don't allow crossposts.  Our
moderation system automatically rejects crossposts without the
moderators ever seeing them in the queue.
Steve Bell - 23 Apr 2008 22:32 GMT
> > Hi Ken,
> >
[quoted text clipped - 47 lines]
> Fred Diether
> Co-moderator  sci.physics.foundations

Hi Fred,

Thanks for this information. I'll see if I can get it added.

Thanks,
Steve
kp - 23 Apr 2008 09:55 GMT
I don't understand what the problem is. The comparison between
experiment and theory can be found here:

http://physics.nist.gov/cuu/Constants/codata.pdf

It starts with the eigenvalues of the Dirac equation and then includes
corrections for the finite mass, QED etc.  The transition energies
agree amazing well.

kp
Jerry - 23 Apr 2008 11:57 GMT
> I don't understand what the problem is. The comparison between
> experiment and theory can be found here:
[quoted text clipped - 4 lines]
> corrections for the finite mass, QED etc.  The transition energies
> agree amazing well.

Thank you, kp!

I'll remember this the next time Steve Bell posts on this
exact same topic using the exact same arguments several
years from now...

:-)

Jerry
Steve Bell - 23 Apr 2008 15:52 GMT
> I don't understand what the problem is. The comparison between
> experiment and theory can be found here:
[quoted text clipped - 6 lines]
>
> kp

Hi kp,

Thanks for this link. As far as I can tell, nowhere in the paper is the
Rydberg constant for hydrogen presented. It is this Rydberg constant I am
discussing, not R_infinity, which is discussed in the link. You may say,
just compute R_H from R_infinity. Yes, please do that. You will get an R_H
value essentially equaling the one given by the Wikipedia site:

http://en.wikipedia.org/wiki/Rydberg_constant

The value is R_H = 10967758.341 m^-1.

It seems logical to think that as time goes by, our values of h, e, m_e,
m_p, etc., have gotten better, and indeed they have. By "better" I mean
closer to what their values are in nature. This means that any equation
using these values gets "better" itself, for whatever it is computing.
Naturally then, some energy equation, such as Dirac's hydrogen energy
equation, should through the years, start providing better and better values
for hydrogen's ground state binding energy, and the associated Rydberg
constant. And once again, by "better" I mean getting closer to the true
physical value. Schroedinger's energy equation should also start getting
better and better, but given hydrogen itself does indeed "outwardly
manifest" relativistic effects, the Schroedinger's equation ought to start
giving values that differ from a hydrogen Rydberg constant derived only from
the spectroscopic data. It should be Dirac's equation that starts to
converge on the observed. Is there any data around that shows us how
Schroedinger's theory has faired over the years? Yes, there is. Please look
at Eisberg and Resnick's text. If you have their 2nd edition, they present a
predicted value using Bohr's theory (identical to Schroedinger's theory). I
believe the values of h, e, m_e, etc., they used were in the 1970's time
frame. The predicted value they give (p. 105, 2nd ed.) is R_H = 10968100
m^-1. Also in that text, on p. 98, they present an observed value of
10967757.6 m^-1. These values have nothing to do with the sophistication of
the quantum text. Even sophisticated quantum texts (e.g., Merzbacher's
"Quantum Mechanics") goes over the non-relativistic Schroedinger's theory
first. As far as the "sophistication" of the observed value, that's given by
the accuracy of the spectroscopic machinery, and apparently back in the
1970s, that was good enough to provide a standard error of 1.2 m^-1, not too
bad. Ok, look at how Schroedinger's theory has faired. It has converged
nearly exactly upon the observed. Certainly, Dirac's theory should have
faired better, since it includes relativistic effects, and QED effects, etc.
The value I quoted from the refereed paper is 109678771.17374 m^-1. This
value was computed using values of h, e, m_e, etc. from the 1990s. Since I
don't have the 1990s values, I can't make a Schroedinger's prediction, but I
highly suspect it would very nearly equal a prediction using today's values,
given by the Wikipedia site. The difference between the Dirac prediction and
the observed is 118 m^-1. The difference between the Schroedinger prediction
and the observed is 0.741 m^-1. There is a gigantically significant
difference between the two theories in their predictions. And it is
Schroedinger's non-relativistic theory that wins, hands down. The observed
value of nearly 10967757.6 m^-1 has been around for decades. The reason why
it has not changed much is because our spectroscopic machinery has been
pretty good for decades, and this value is not some merger between theory
and data. Even if it were, why would the Schroedinger non-relativistic
theory be the one used to bias the data? You would think if there were some
purposeful biasing of the data, one would use Dirac's theory, not
Scroedinger's theory.

This is my basic contention: An accurate observed value for R_H has been
around for decades, and apparently it is now the non-relativistic
Schroedinger's theory that has converged upon this value, not the "more
sophisticated" Dirac theory. This is most perplexing.

Steve Bell
Androcles - 23 Apr 2008 16:56 GMT
This message is brought to you by Androcles
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| > I don't understand what the problem is. The comparison between
| > experiment and theory can be found here:
[quoted text clipped - 71 lines]
|
| Steve Bell

Why should a "non relativistic" theory be perplexing?
I'm not perplexed by it.
Why did the crank Einstein say
the speed of light from A to B is c-v,
the speed of light from A to B is c+v,
and the time each way is the same?
There's the root of "relativistic theory" (aka crackpottery), resulting
in perplexity.
Steve Bell - 23 Apr 2008 22:16 GMT
> This message is brought to you by Androcles
>   http://www.androcles01.pwp.blueyonder.co.uk/
>
> | "kp" <4vector@gmail.com> wrote in message

news:ff602c99-ecc7-4a86-8f17-2f70201dc6d7@z72g2000hsb.googlegroups.com...
> | > I don't understand what the problem is. The comparison between
> | > experiment and theory can be found here:
[quoted text clipped - 95 lines]
> There's the root of "relativistic theory" (aka crackpottery), resulting
> in perplexity.

Hi Androcles,

It's not the non-relativistic theory that's perplexing. It's the fact that a
non-relativistic theory agrees with the experimental data (as far as I can
tell), and that perplexes me, because I accept the validity of both SR and
GR. I hope people following this thread do not get the impression that I
disagree with relativity. Quite the contrary. I accept it wholeheartedly. In
fact, it's only by using relativity that I think there is resolution to the
disagreement between predicted and observed.

Steve
Androcles - 23 Apr 2008 23:04 GMT
This message is brought to you by Androcles
 http://www.androcles01.pwp.blueyonder.co.uk/

| > This message is brought to you by Androcles
| >   http://www.androcles01.pwp.blueyonder.co.uk/
[quoted text clipped - 119 lines]
| tell), and that perplexes me, because I accept the validity of both SR and
| GR.

Oh, I see.

I hope people following this thread do not get the impression that I
| disagree with relativity. Quite the contrary. I accept it wholeheartedly. In
| fact, it's only by using relativity that I think there is resolution to the
| disagreement between predicted and observed.

Maybe you missed my question. I'll repeat it and you answer it.

Why did the malignant idiot and imbecile Albert Einstein, creator of your
crank religion, say:
the speed of light from A to B is c-v,
the speed of light from A to B is c+v,
and the time each way is the same?

'the ``time'' required by light to travel from A to B equals the ``time'' it
requires to travel from B to A.' -- Albert Nitwit Einstein, charlatan.
Ref: http://www.fourmilab.ch/etexts/einstein/specrel/www/

I hope people following this thread DO get the impression that I
STRONGLY disagree with CRANK relativity.

No wonder you are perplexed if you actually believe in crackpottery.

Well, at least the the fact that a non-relativistic theory agrees with
the experimental proves your crank religion is flawed. Have a quick
pray to Rabbi St. Albert the Divine to get Nature changed to agree
with his sophisticated stupidity.
Steve Bell - 23 Apr 2008 23:22 GMT
> | Hi Androcles,
> |
[quoted text clipped - 34 lines]
> pray to Rabbi St. Albert the Divine to get Nature changed to agree
> with his sophisticated stupidity.

Hi Andocles,

Why do you have to be so caustic? Until you stop that, I will not consider
what you are saying. And please, do not state to anyone that what I have
presented here in anyway "proves" the invalidity of SR or GR. That would be
a misrepresentation of what I am trying to get across.

Steve
Androcles - 23 Apr 2008 23:41 GMT
Signature

This message is brought to you by Androcles
 http://www.androcles01.pwp.blueyonder.co.uk/

| > | Hi Androcles,
| > |
[quoted text clipped - 43 lines]
|
| Why do you have to be so caustic?

That's just my nature, I'm caustic to most cranks.

| Until you stop that, I will not consider
| what you are saying.

Bigotry will get you everywhere, I'm sure. Do carry on being perplexed.
Picture of Steve Bell:
   http://www.concurringopinions.com/archives/images/ostrich.jpg

| And please, do not state to anyone that what I have
| presented here in anyway "proves" the invalidity of SR or GR. That would be
| a misrepresentation of what I am trying to get across.

The only thing you've gotten across is your blind faith in the word of a
con artist and now you are too embarrassed to admit you've been
hoodwinked.

I have proved that you don't understand your own faith by simply pointing
out that you cannot answer my question.
kp - 23 Apr 2008 17:15 GMT
> You may say,
> just compute R_H from R_infinity. Yes, please do that.

I'll pass on this.  I'm not asking the question.

> You will get an R_H
> value essentially equaling the one given by the Wikipedia site:
>
> http://en.wikipedia.org/wiki/Rydberg_constant
>
> The value is R_H = 10967758.341 m^-1.

Let us say it is.

>. Please look
> at Eisberg and Resnick's text. If you have their 2nd edition, they present a
[quoted text clipped - 3 lines]
> m^-1. Also in that text, on p. 98, they present an observed value of
> 10967757.6 m^-1.

I don't have the book with with, but I believe you.

> The value I quoted from the refereed paper is 109678771.17374 m^-1. This
> value was computed using values of h, e, m_e, etc. from the 1990s. Since I
[quoted text clipped - 4 lines]
> and the observed is 0.741 m^-1. There is a gigantically significant
> difference between the two theories in their predictions.

The experimental value you quote was found forty years ago, do you
think better measurements have been done since then. I'm not an
experimentalist but maybe determining the ionization energy is not as
accurately done as finding the transitions between the low lying bound
states. You can see from the CODATA paper that even in the low energy
states the uncertainty can vary over 5 or 6 orders of magnitude. At
this point I would say that there is nothing more than experimental
uncertainty for any disagreement.  Otherwise any argument would
require saying quantum mechanics (field theory) gets the energies
given in CODATA right to parts in a trillion but gets the ionization
energy wrong. These two just don't add up.

kp
Ken S. Tucker - 23 Apr 2008 20:30 GMT
> > You may say,
> > just compute R_H from R_infinity. Yes, please do that.
[quoted text clipped - 41 lines]
> energy wrong. These two just don't add up.
> kp

Unfortunately, the standard kilogram is drifting.
There is a discussion about that in s.p.research.

We redefined our mass using,
http://physics.trak4.com/MST_Mass-Definition.pdf
(to replace 1000 Napolean penises :-), to place
on the time standard.
Regards
Ken S. Tucker
Steve Bell - 23 Apr 2008 22:02 GMT
> > You may say,
> > just compute R_H from R_infinity. Yes, please do that.
[quoted text clipped - 42 lines]
>
> kp

Hi kp,

Thanks for responding. You, sir, more than anyone else so far, have
presented the best counter argument to my hypothesis. I'm sure you know what
my hypothesis is, and it all hinges on what the true, physical, natural
value of hydrogen's ground state binding energy is, and its associated
Rydberg constant. Let me describe what I mean by this. It involves a thought
experiment. There exists a hydrogen atom in its ground state. An EM wave
washes over this hydrogen atom, and the atom ionizes. The EM wave has a
wavelength. Invert this wavelength. This is what I mean by the true,
physical, natural Rydberg constant for hydrogen. Notice that no mention of
any theory was made. Does this hydrogen atom have a proton with infinite
mass? Obviously not. The proton and electron constitute a 2-body system, and
each revolves about the center of mass of the system. It is this physical
condition that dictates exactly what physical wavelength of EM radiation
ionizes hydrogen. Is the electron undergoing natural relativistic effects?
Yes, absolutely, I think so. Once again, it is the true, physical fact of
the existence of relativistic effects that influences exactly what physical
wavelength of EM radiation ionizes hydrogen.  Is this the correct
interpretation of what the observed value of 10967757.6 m^-1 represents,
that is, that it is close to the true, physical, natural, "not influenced by
any theory" Rydberg constant value? The fact that this value has been around
for decades strongly suggest to me that, yes, the true, physical natural
Rydberg constant for hydrogen is real close to 10967757.6 m^-1. Will we ever
be able to quantify R_H through experimentation exactly? Obviously not,
because we will never be able to construct infinitely precise and infinitely
accurate experimental machinery. But like I said, I highly suspect that the
value of 10967757.6 m^-1 (from the Eisberg and Resnick text) or the value of
10967759 m^-1 (from the PPT slides, and not much different) are both very
close to the natural value. I feel these number have not been influenced by
some biasing by a theory, except perhaps by the application of the empirical
Rydberg equation itself, which is empirical, and not based on any of the QM
theories discussed here. I will discuss the energy level transition issue,
but the issue of not being biased by a theory will play a strong part in
what I have to say. Is it true that the energy transition levels presented
in the CODATA paper have not been biased in anyway by theory? Please see the
CODATA page at:

http://physics.nist.gov/Pubs/guidelines/sec2.html#note

It is stated: "The nature of an uncertainty component is conditioned by the
use made of the corresponding quantity, that is, on how that quantity
appears in the mathematical model that describes the measurement process."
What "mathematical model" do you think was used to "describe the measurement
process" that generated the transition frequencies? It appears to me from
the CODATA paper you provided a link to, it was QED itself, and then it's a
no-brainer to understand why a post-experimentation prediction using QED
would agree with the "data."

Yes, I absolutely would think better measurements have been done since the
1970s. And I've tried mightily to find a modern accurate observed value of
R_H, but I cannot find one. It's as if this value is simply not produced
anymore, which might be telling in and of itself. So, please, kp, if you can
find a modern, accurate, experimentally determined value of R_H, I would be
most appreciative (please give a reference if you do). I would be very
surprised if it would differ significantly from the observed values I have
quoted, which looks to be in significantly greater alignment with
Schroedinger's non-relativistic theory than Dirac's relativistic theory.
There would have to be a large standard error on the Dirac-theory-based
prediction, used to then construct a confidence interval made using the
ostensibly large standard error, which would then cause an overlap with the
observed using the small +/- 1.4 m^-1 confidence interval one can construct
around these observed values, even using the observational standard error
back in the 1970s quoted by Eisberg and Resnick. Also, if indeed there was
such a large random error in the Dirac prediction, and a "significant"
random error in the observed (if you want to call +/- 1.4 m^-1 "bad", which
I don't, relatively speaking), it would be an amazing coincidence that the
difference between a modern Dirac theory prediction and the observed would
end up equaling 1.8 x 10^-4 eV. This value is what the first order
relativistic effects are, according to Eisberg and Resnick (see p. 286,
where a figure directly states the first order relativistic effects amount
to 1.81 x 10^4 eV). It appears to me that I can confidently say, there are
more types of relativistic effects going on inside of hydrogen, above and
beyond the simple specially relativistic effects incorporated in Dirac's
theory.

All I am doing is the same thing that was done in the PPT slides at:

http://www.lancs.ac.uk/users/spc/teaching/py301/phys301.htm

See part 5, page 9. The fact that these slides are for only a junior level
college class (I presume, because of the 301 number) has absolutely nothing
to do with anything. The theory that is claimed to be in "fantacially good
agreement" is Schroedinger's non-relativistic theory. This theory is
presented in almost all advanced QM text books. The accuracy of the observed
value presented (+/- 1 m^-1) has nothing to do with the fact this a junior
level college presentation. This accuracy could also be shown in any
presentation at any level, because conceptually it doesn't involve theory,
it's just an experimental error. If there is indeed a "fantastically good
agreement" with Schroedinger's non-relativistic theory, there cannot be a
"fantastically good agreement" with Dirac's relativistic theory. The
theories are too significantly different, by the amount of relativistic
effects they incorporate. None for Schroedinger, specially relativistic for
Dirac.

Steve
Steve Bell - 24 Apr 2008 05:36 GMT
> I will discuss the energy level transition issue,
> but the issue of not being biased by a theory will play a strong part in
[quoted text clipped - 12 lines]
> no-brainer to understand why a post-experimentation prediction using QED
> would agree with the "data."

Here is a statement from the CODATA paper that kp referenced
(http://physics.nist.gov/cuu/Constants/codata.pdf):

"First, although it is generally agreed that the correctness and over-all
consistency of the basic theories and experimental methods of physics can be
tested by comparing values of particular fundamental constants obtained from
widely differing experiments, throughout this adjustment, as a working
principle, we assume the validity of the physical theory that necessarily
underlies it. This includes special relativity, quantum mechanics, quantum
electrodynamics (QED), the Standard Model of particle physics,...."

What this means to me, is that all of the hydrogen transition frequencies
given in this paper are a blend of the actually observed frequencies, and
"corrections" to those frequencies based on special relativity, quantum
mechanics, and quantum electrodynamics (QED). In other words, the values of
the transition frequencies quoted are indeed very heavily biased by these
theories. This is very similar to Bayesian estimation in statistics, where
the final value quoted from some experiment is a blend between the data
actually observed, and some theoretical prediction of what the data should
have turned out to be. There is another estimation philosophy in statistics,
called Fisherian estimation theory (after the great English statistician, R.
Fisher, the inventor of maximum likelihood (MLE) estimation) that says hooey
to that, just give me the unbiased data, and I'll compute my estimates based
on that, without blending in any preconceived a priori belief in what the
result should be. I bet you can tell, I'm Fisherian in my statistical
estimation theory philosophy. I was trained like that when I got my MS in
Statistics, thank heaven. Apparently, the CODATA people are very Bayesian in
philosophy, and if you accept the correct thing to do is to modify the
results of an experiment with your preconceived ideas of what the data
should have turned out to be, that's very suspect science, imo. Dr. Fisher
must be rolling over in his grave at what has happened in modern physics.
It's a self fulfilling iteration between theory and experiment, and as a
result, there probably is no chance something new and revolutionary will
ever be seen again.

Steve
N:dlzc D:aol T:com (dlzc) - 24 Apr 2008 06:27 GMT
Dear Steve Bell:

...
> It's a self fulfilling iteration between theory and
> experiment, and as a result, there probably is
> no chance something new and revolutionary will
> ever be seen again.

Oh, I doubt that...
http://uk.reuters.com/article/oddlyEnoughNews/idUKL229032322008042

http://news.yahoo.com/s/afp/20080417/od_afp/russialabouroffbeat_080417161913

David A. Smith
Androcles - 24 Apr 2008 07:25 GMT
Signature

This message is brought to you by Androcles
 http://www.androcles01.pwp.blueyonder.co.uk/

| Dear Steve Bell:
|
[quoted text clipped - 6 lines]
| Oh, I doubt that...
| http://uk.reuters.com/article/oddlyEnoughNews/idUKL229032322008042

http://news.yahoo.com/s/afp/20080417/od_afp/russialabouroffbeat_080417161913

| David A. Smith

You are a LIAR, Smiffy.
Steve Bell - 24 Apr 2008 15:29 GMT
> Dear Steve Bell:
>
[quoted text clipped - 6 lines]
> Oh, I doubt that...
> http://uk.reuters.com/article/oddlyEnoughNews/idUKL229032322008042

http://news.yahoo.com/s/afp/20080417/od_afp/russialabouroffbeat_080417161913

> David A. Smith

Hi David,

I went to the first link, but it said the page was not found. I went to the
second link, and it was about a drunk Russian. This does bring up an
interesting topic for discussion. Do you believe that something will either
incorporate QM as a special case, as for example, GR incorporated Newtonian
mechanics as a special case, or out right replace QM? I suppose someone
could argue that all of what is called QM (QED, QFT, QCD, etc.) has been
incorporated underneath superstring theory, but to me, since it is based on
the postulates that Dirac originally formulated, string theory is really
just another "topic" underneath QM. For the string theorists to say "this is
the final theory of everything" is very reminiscent of the Newtonian
physicists who thought basically the exact same thing before the relativity
revolution, and we know how that turned out. I wonder if there really ever
can be an "end of physics".

If there is indeed this self fulfilling iteration between theory and
experiment now in QM, I would have to believe it may be impossible for
anything to overcome such a bias. If the actual experimental data is heavily
biased by  theory, there likely is no chance that theory will ever disagree
with experimentation, and the advance of science comes to a dead halt.

Steve
dlzc - 24 Apr 2008 16:46 GMT
> "N:dlzcD:aol T:com (dlzc)" <dl...@cox.net> wrote in messagenews:9TUPj.170803$nr1.117681@newsfe13.phx...> Dear Steve Bell:
>
[quoted text clipped - 5 lines]
>
> > Oh, I doubt that...

http://uk.reuters.com/article/oddlyEnoughNews/idUKL2290323220080422
... the link was missing the final "2"

> I went to the first link, but it said the page was not
> found. I went to the second link, and it was about a
> drunk Russian.

They were just a mild "pokes" at "nothing new will ever be seen
again".

> This does bring up an interesting topic for discussion.
> Do you believe that something will either incorporate
> QM as a special case, as for example, GR incorporated
> Newtonian mechanics as a special case, or out right
> replace QM?

QM reduces the entire Universe to a finite local effect.
GR paves over the discrete foundation of the Universe, and treats it
as infinitely differentiable.

They will both have to be "bent" in ways we cannot yet see, and
certainly not yet (?) have the mathematical tools to merge the two.

> I suppose someone could argue that all of what is
> called QM (QED, QFT, QCD, etc.) has been incorporated
> underneath superstring theory, but to me, since it is
> based on the postulates that Dirac originally
> formulated, string theory is really just another
> "topic" underneath QM.

Not quite true.  String theory intentionally has "extension", so
variable effect at one end of the string over the other.  It has the
inherent capacity to overcome the limitations of QM in describing a
"statistical" Universe.

> For the string theorists to say "this is the
> final theory of everything" is very reminiscent of
> the Newtonian physicists who thought basically the
> exact same thing before the relativity revolution,
> and we know how that turned out.

You have to get to the top of the hill in front of you, before you can
see the next hill.  Once we know what string theory fails at
predicting correctly, we will be looking at the next hill.

> I wonder if there really ever can be an "end of
> physics".

The box can never contain itself.  So no.

> If there is indeed this self fulfilling iteration
> between theory and experiment now in QM, I would
> have to believe it may be impossible for anything
> to overcome such a bias.

No such bias in science, only those that write about science for
popular digestion.  Science requires different tests, and if edges are
detected, the theory is extended.  If it is complete over its domain,
little research is carried on in it.

> If the actual experimental data is heavily biased
> by  theory, there likely is no chance that theory
> will ever disagree with experimentation, and the
> advance of science comes to a dead halt.

Nature is consulted.  If Nature laughs we try again.  *No one* in
Science thinks they have a handle on Truth.  Nor is Truth accessible.
All of Science is estimation / approximation.  And no one is
particularly happy with the "arbitrary constants" that make QM work so
successfully.  Or they shouldn't be...

David A. Smith
Steve Bell - 24 Apr 2008 17:35 GMT
On Apr 24, 7:29 am, "Steve Bell" <sb...@starband.net> wrote:
> "N:dlzcD:aol T:com (dlzc)" <dl...@cox.net> wrote in messagenews:9TUPj.170803$nr1.117681@newsfe13.phx...> Dear Steve Bell:
>
[quoted text clipped - 5 lines]
>
> > Oh, I doubt that...

http://uk.reuters.com/article/oddlyEnoughNews/idUKL2290323220080422
... the link was missing the final "2"

> I went to the first link, but it said the page was not
> found. I went to the second link, and it was about a
> drunk Russian.

They were just a mild "pokes" at "nothing new will ever be seen
again".

> This does bring up an interesting topic for discussion.
> Do you believe that something will either incorporate
> QM as a special case, as for example, GR incorporated
> Newtonian mechanics as a special case, or out right
> replace QM?

QM reduces the entire Universe to a finite local effect.
GR paves over the discrete foundation of the Universe, and treats it
as infinitely differentiable.

They will both have to be "bent" in ways we cannot yet see, and
certainly not yet (?) have the mathematical tools to merge the two.

> I suppose someone could argue that all of what is
> called QM (QED, QFT, QCD, etc.) has been incorporated
> underneath superstring theory, but to me, since it is
> based on the postulates that Dirac originally
> formulated, string theory is really just another
> "topic" underneath QM.

Not quite true.  String theory intentionally has "extension", so
variable effect at one end of the string over the other.  It has the
inherent capacity to overcome the limitations of QM in describing a
"statistical" Universe.

> For the string theorists to say "this is the
> final theory of everything" is very reminiscent of
> the Newtonian physicists who thought basically the
> exact same thing before the relativity revolution,
> and we know how that turned out.

You have to get to the top of the hill in front of you, before you can
see the next hill.  Once we know what string theory fails at
predicting correctly, we will be looking at the next hill.

> I wonder if there really ever can be an "end of
> physics".

The box can never contain itself.  So no.

> If there is indeed this self fulfilling iteration
> between theory and experiment now in QM, I would
> have to believe it may be impossible for anything
> to overcome such a bias.

No such bias in science, only those that write about science for
popular digestion.  Science requires different tests, and if edges are
detected, the theory is extended.  If it is complete over its domain,
little research is carried on in it.

> If the actual experimental data is heavily biased
> by theory, there likely is no chance that theory
> will ever disagree with experimentation, and the
> advance of science comes to a dead halt.

Nature is consulted.  If Nature laughs we try again.  *No one* in
Science thinks they have a handle on Truth.  Nor is Truth accessible.
All of Science is estimation / approximation.  And no one is
particularly happy with the "arbitrary constants" that make QM work so
successfully.  Or they shouldn't be...

David A. Smith

Hi David,

Do you think that string theory uses the same statistical interpretation as
laid down by Max Born? That is, that the complex conjugate of a solution of
the Schroedinger equation, times itself, yields a real value that is
proportional to a probability? It seems to me it does. For that reason, it's
hard to see how string theory can overcome how QM describes a statistical
universe, since if what I said is true, string theory itself is just as
"statistical" as QM.

This brings up another interesting question. Is the external world really
statistical, or is it really deterministic? As you probably know, there is a
rapidly advancing branch of science called Chaos Theory. Contrary to the
implications of its name, the external world is viewed as deterministic, but
extremely complicated. One of its tenets, I think, is that the phenomenal
deterministic complexity of a "nonlinear deterministic system" causes it
only to look stochastic, but it really isn't. Perhaps that's what's really
going on, even in an atom. An electron really is a particle, coasting along
on a very complicated deterministic orbit. It just looks stochastic to us,
but in fact it is not. But because the motion is so complicated, the only
thing we can do is describe it statistically. There is also being developed
an attempt at a merger with QM, which if I am not wrong, is called Quantum
Chaos. But to me, there would have to be a fundamental break with the
underlying tenet of QM that the external world is truthfully stochastic for
this to succeed.

With regards to these discussions here, perhaps the following is true.
Today, the CODATA folks produce a "consistent set of fundamental constants."
I think I see what they mean by that. The final values they present are
consistent with the current accepted theories of modern physics, relativity,
QM, etc. As it looks to me, no longer are the data used (e.g., the actual
spectroscopic data) in an unbiased manner. Of course, if you accept the
validity of these theories, this biasing is a positive thing, not a negative
thing. I think perhaps, the observed values of the Rydberg constant for
hydrogen that I have quoted here were experimentally derived prior to the
enforcing of this bias, and in fact are only based on the raw, unbiased
spectroscopic data. If so, I am even more convinced that something is amiss,
because that's exactly the type of Rydberg constant for hydrogen that I like
to use, and that I think should be used, one one that only nature itself has
dictated its value, uncorrupted by any theory, including mine. It may be
that around about the time these consistent sets were started to be
generated, that's when these unbiased, truthfully experimentally derived
Rydberg constants for hydrogen were no longer being generated, and that's
the reason why I can't find one today.

Steve
dlzc - 24 Apr 2008 23:08 GMT
Dear Steve Bell:

...
> Do you think that string theory uses the same
> statistical interpretation as laid down by Max
> Born? That is, that the complex conjugate of a
> solution of the Schroedinger equation, times
> itself, yields a real value that is
> proportional to a probability?

Except that it can now have directional properties.

> It seems to me it does. For that reason, it's
> hard to see how string theory can overcome how
> QM describes a statistical universe, since if
> what I said is true, string theory itself is
> just as "statistical" as QM.

Except that it is now different.  And keep in mind that GR itself is
very much "statistical", since it only applies for large collections
of quantum objects, and those distributed.

> This brings up another interesting question. Is
> the external world really statistical,

As we perceive it, yes.

> or is it really deterministic?

All of Science assumes deterministic in everything, the statistical
bit simply applies determinism in a more slippery way.

> As you probably know, there is a rapidly
> advancing branch of science called Chaos
[quoted text clipped - 6 lines]
> stochastic, but it really isn't. Perhaps
> that's what's really going on, even in an atom.

Probably not. "Really going on" makes assumptions we cannot make.

> An electron really is a particle,

No, it is not an abstract word made up with large macroscopic system
bias.

> coasting along on a very complicated
> deterministic orbit. It just looks stochastic
> to us, but in fact it is not.

What you are straining at is how the system of nucleus + electron
"attaches" to the Universe at large.  You should not spend effort
trying to infer what the electron "really" is in this context.

> But because the motion is so complicated, the only
> thing we can do is describe it statistically.

No, "motion", "complexity" are your attempt to make the electron a
billiard ball, its orbital some sort of path around the nucleus, and
the nucleus a billiard ball whose electrical field is incidentally
*completely neutralized at all scales* by this orbitting electron and
does it without producing a magnetic field.

> There is also being developed an attempt at a
> merger with QM, which if I am not wrong, is
> called Quantum Chaos. But to me, there would
> have to be a fundamental break with the
> underlying tenet of QM that the external world
> is truthfully stochastic for this to succeed.

I don't worry about what "props" are doing.

> With regards to these discussions here, perhaps
> the following is true.  Today, the CODATA folks
[quoted text clipped - 3 lines]
> consistent with the current accepted theories
> of modern physics, relativity, QM, etc.

I would say that is right.  The values themselves derive from
application of theory, and are (sometimes) far removed from actual
measurement.

> As it looks to me, no longer are the data used
> (e.g., the actual spectroscopic data) in an
> unbiased manner.

Load the terms politically / emotionally if you like.  But a common
language is in use.  Add new "words" if you need to, but don't
complain about the (current) meanings.

...
> It may be that around about the time these
> consistent sets were started to be generated,
> that's when these unbiased, truthfully
> experimentally derived Rydberg constants for
> hydrogen were no longer being generated, and
> that's the reason why I can't find one today.

I don't know what version of Reality you think you are in, but the
rest of us depend on "the shoudlers of giants" to get our jobs done.
"Truth" is obtainable in the courtroom, or in philosophy.  The rest of
us depend on measurement and reported results.  You do realize that
the CODATA values were obtained by experiment, and the methods used in
data reduction are published.  You can "back into" statistical
measures of actual data without too much difficulty.

You are obsessed with inanities.  You have a sharp mind.  Why do you
work on dirt with it?  Bored?

David A. Smith
Steve Bell - 25 Apr 2008 02:51 GMT
Dear Steve Bell:

On Apr 24, 9:35 am, "Steve Bell" <sb...@starband.net> wrote:
...
> Do you think that string theory uses the same
> statistical interpretation as laid down by Max
> Born? That is, that the complex conjugate of a
> solution of the Schroedinger equation, times
> itself, yields a real value that is
> proportional to a probability?

>> Except that it can now have directional properties.

Hi dltz,

I don't know what that means, but that's my fault. I'll have to study up
more on this.

> It seems to me it does. For that reason, it's
> hard to see how string theory can overcome how
> QM describes a statistical universe, since if
> what I said is true, string theory itself is
> just as "statistical" as QM.

> > Except that it is now different.  And keep in mind that GR itself is
>>  very much "statistical", since it only applies for large collections
>> of quantum objects, and those distributed.

Personally, I don't view GR as statistical in any way. To me, it is a
completely deterministic theory.

> This brings up another interesting question. Is
> the external world really statistical,

>> As we perceive it, yes.

I would suppose then, you disagree with Chaos Theory.

> or is it really deterministic?

>> All of Science assumes deterministic in everything, the statistical
>> bit simply applies determinism in a more slippery way.

To me, the external world is either stochastic (I usually use "stochastic"
and "statistical" interchangeably) or deterministic. I don't think it can be
both. It has to be, to me, one or the other.

> As you probably know, there is a rapidly
> advancing branch of science called Chaos
[quoted text clipped - 6 lines]
> stochastic, but it really isn't. Perhaps
> that's what's really going on, even in an atom.

>> Probably not. "Really going on" makes assumptions we cannot make.

I personally believe like Einstein, that there is in fact "an external
world, independent of the perceiving subject." If the external world is
"this" and we think it's "that" this doesn't at all change the fact that
it's really "that." What we think the external world "is" doesn't at all
change what it really "is." Of course, when the external world is "this" and
we think it's the same "this", then we should celebrate. Unfortunately, it
usually is difficult to realize that we've gotten it correct. In fact, we
actually really never know with 100% certainty that we've gotten it right.

> An electron really is a particle,

>> No, it is not an abstract word made up with large macroscopic system
>> bias.

I'm sure you can see from my previous comments, that I think an electron
truthfully physically exists. I don't believe it is just an abstract
concept.

> coasting along on a very complicated
> deterministic orbit. It just looks stochastic
> to us, but in fact it is not.

>> What you are straining at is how the system of nucleus + electron
>> "attaches" to the Universe at large.  You should not spend effort
>> trying to infer what the electron "really" is in this context.

If by "attaches to the universe," you are referring to something like Mach's
Principle, that's an interesting way to say it. I think any time spent
thinking about what an electron "really is" is time very well spent.

> But because the motion is so complicated, the only
> thing we can do is describe it statistically.

>> No, "motion", "complexity" are your attempt to make the electron a
>> billiard ball, its orbital some sort of path around the nucleus, and
>> the nucleus a billiard ball whose electrical field is incidentally
>> *completely neutralized at all scales* by this orbitting electron and
>> does it without producing a magnetic field.

Yes, that's basically what I believe. Also, I very much believe that as the
electron orbits about the nucleus, it does indeed generate an orbital-based
magnetic field. Interestingly, there is one big gigantic problem that I've
never seen addressed about viewing an electron in an orbit. If indeed an
electron orbits in an orbit similar to a Newtonian orbit, the electron would
forever stay in a single plane. I believe we have experimental evidence that
this is not the case. For example, the electron in ground state hydrogen
indeed "lives" in a spherical shell around the nucleus. Believe it or not,
there is an orbit theoretical approach that can explain this.

> There is also being developed an attempt at a
> merger with QM, which if I am not wrong, is
> called Quantum Chaos. But to me, there would
> have to be a fundamental break with the
> underlying tenet of QM that the external world
> is truthfully stochastic for this to succeed.

>> I don't worry about what "props" are doing.

What's a "prop"?

> With regards to these discussions here, perhaps
> the following is true.  Today, the CODATA folks
[quoted text clipped - 3 lines]
> consistent with the current accepted theories
> of modern physics, relativity, QM, etc.

>> I would say that is right.  The values themselves derive from
>> application of theory, and are (sometimes) far removed from actual
>> measurement.

I'm glad you see this.

> As it looks to me, no longer are the data used
> (e.g., the actual spectroscopic data) in an
> unbiased manner.

>> Load the terms politically / emotionally if you like.  But a common
>> language is in use.  Add new "words" if you need to, but don't
>> complain about the (current) meanings.

To me, it sounds strange you would say this given what you have said above.
...
> It may be that around about the time these
> consistent sets were started to be generated,
> that's when these unbiased, truthfully
> experimentally derived Rydberg constants for
> hydrogen were no longer being generated, and
> that's the reason why I can't find one today.

>> I don't know what version of Reality you think you are in, but the
>> rest of us depend on "the shoudlers of giants" to get our jobs done.
[quoted text clipped - 3 lines]
>> data reduction are published.  You can "back into" statistical
>> measures of actual data without too much difficulty.

Whatever version of reality I think I'm in is irrelevant to what the
external world really is. I believe that, but it doesn't stop me from trying
to figure out the true nature of an external world that I think exists
independently of me. I really do believe there is a "truth" about the
external world, and I am convinced now more than ever, it is not what modern
physics thinks it is. And I completely realize there are thousands of
extremely talented folks out there who would say I am wrong. And I
completely realize that right now, it is highly unlikely I am correct. But
remember, lots of folks thought relativity was highly likely to be incorrect
before it was proven (imo) to be correct. Now, you may think I am an
egomaniac by making such a statement, and I would understand why. But what
if I'm right?

>> You are obsessed with inanities.  You have a sharp mind.  Why do you
>> work on dirt with it?  Bored?

Well thank you, sir, but I highly suspect your complementary opinion about
the sharpness of my mind is an opinion of an extreme minority. I have, in
the past, been called a complete idiot, even by people I really do respect
scientifically (like Bilge, etc.)

For the past several years, I've worked as a synthetic aperture radar (SAR)
scientist. When I started to learn the theory behind SAR, I saw that in many
ways, it was very similar to QM. There is even a paper written back in the
1940s by a man named Gabor, who linked together the analytic signal process
theory of SAR to QM, deriving specific versions of the uncertainty principle
(UP) applicable to SAR theory. I eventually saw the same flaws (imo) in the
union of the physics and statistics in SAR theory that had occurred in QM.
It has a lot to do with the rather strange interpretations of the UP that
both of these fields maintain, and that I think are incorrect This
concentrating on these ideas in the past few years have given me hope that I
may convince people I might be correct, so I'm back trying again. Alas,
though, I present much of the same arguments I have in the past, and the
anti-response is much the same, and you know, as someone pointed out, it is
getting rather nauseous. Another reason I post on this is because I think I
know an answer to the "problem" that I see. But if I can't get anyone to
admit there is in fact a problem, then what's the point in presenting a
solution to a "problem" that no one thinks really exists? Sometimes, though,
by presenting the solution to some supposed "non problem," others see the
problem was actually there all along. But I think I'll hold off in saying
what I think is the solution to the observed-predicted hydrogen Rydberg
constant "problem." I have a thick hide, but maybe not so thick that I can
take another barrage of bullets, which I know would be shot at me, if not an
atomic bomb. Probably by then, a lot of folks would think the only way to
get rid of this horrible infestation named "Bell" would be to nuke it to
death.

And even from the stinkiest of dirt, sometimes beautiful flowers can be
grown.

>> David A. Smith

Steve
Steve Bell - 25 Apr 2008 03:17 GMT
> I personally believe like Einstein, that there is in fact "an external
> world, independent of the perceiving subject." If the external world is
> "this" and we think it's "that" this doesn't at all change the fact that
> it's really "that."

Sorry, typo, I meant to say:

I personally believe like Einstein, that there is in fact "an external
world, independent of the perceiving subject." If the external world is
"this" and we think it's "that" this doesn't at all change the fact that
it's really "this."

Jeez, for a second it looked like I slipped into the human-egocentric
opinion that "the world is actually what we think it is."

Steve
Androcles - 25 Apr 2008 07:51 GMT
Signature

This message is brought to you by Androcles
 http://www.androcles01.pwp.blueyonder.co.uk/

| > I personally believe like Einstein, that there is in fact "an external
| > world, independent of the perceiving subject." If the external world is
[quoted text clipped - 12 lines]
|
| Steve

The opinion of mystics and shaman... and cranks. "We" don't agree
with *you*, and we think it's "that" doesn't at all change the fact that
it's really "that" even though you hallucinate it is "this".
N:dlzc D:aol T:com (dlzc) - 25 Apr 2008 05:49 GMT
Dear Steve Bell:

Interesting indenting you have used... restoring.

> Dear Steve Bell:
>
[quoted text clipped - 11 lines]
> I don't know what that means, but that's my
> fault. I'll have to study up more on this.

"Strings" were chosen as the basic model, because they are
simple, and have non-negligible extent in one axis.

>>> It seems to me it does. For that reason, it's
>>> hard to see how string theory can overcome how
[quoted text clipped - 9 lines]
> Personally, I don't view GR as statistical in any
> way. To me, it is a completely deterministic theory.

All of science is deteministic.  GR only applies to populations.

>>> This brings up another interesting question. Is
>>> the external world really statistical,
[quoted text clipped - 3 lines]
> I would suppose then, you disagree with Chaos
> Theory.

No, not at all.  The determinism is still there.

>>> or is it really deterministic?
>
[quoted text clipped - 6 lines]
> interchangeably) or deterministic. I don't think it
> can be both. It has to be, to me, one or the other.

Given a certain large number of unstable nucleii, "half" of them
will be gone in one half-life.  Not saying which ones have
decayed, but the population is well behaved.  It *is*
deterministic.

>>> As you probably know, there is a rapidly
>>> advancing branch of science called Chaos
[quoted text clipped - 9 lines]
>> Probably not. "Really going on" makes
>> assumptions we cannot make.

[substituting your correction]
> I personally believe like Einstein, that there is
> in fact "an external world, independent of the
[quoted text clipped - 9 lines]
> really never know with 100% certainty that
> we've gotten it right.

Well, I have been toying with two mutually orthogonal time
axes... one dependent on any particular "configuration", from
which spacetime develops back to the Big Bang, and the other
subject to Will.

>>> An electron really is a particle,
>
[quoted text clipped - 4 lines]
> that I think an electron truthfully physically exists.
> I don't believe it is just an abstract concept.

Electrons do really exist.  But they are not billiard balls, and
saying "particles" does not make them particle-like.  You test
for particle, you get particle... it is your "model" that it
responds to.

>>> coasting along on a very complicated
>>> deterministic orbit. It just looks stochastic
[quoted text clipped - 10 lines]
> thinking about what an electron "really is" is
> time very well spent.

Not when it is part of a system, and part of the system's rest
mass is "elsewhere".  When you analyze a neutral atom (ground
state or not) you *must* also include the butcher's thumb on the
scale.

>>> But because the motion is so complicated, the only
>>> thing we can do is describe it statistically.
[quoted text clipped - 10 lines]
> nucleus, it does indeed generate an orbital-based
> magnetic field.

But it doesn't.  It cannot, for it will radiate energy, and fall
into the nucleus.

> Interestingly, there is one big gigantic problem
> that I've never seen addressed about viewing an
[quoted text clipped - 6 lines]
> around the nucleus. Believe it or not, there is an
> orbit theoretical approach that can explain this.

Schroedinger.  And I believe that I've seen images of actual
atomic structure using atomic force microscopes.  A point
particle (the electron), as part of a system, inflates to a
"balloon".

>>> There is also being developed an attempt at a
>>> merger with QM, which if I am not wrong, is
[quoted text clipped - 6 lines]
>
> What's a "prop"?

The stuff we measure are props in a Play.

>>> With regards to these discussions here, perhaps
>>> the following is true.  Today, the CODATA folks
[quoted text clipped - 21 lines]
> To me, it sounds strange you would say this given
> what you have said above.

Wave, or particle.
Common language, or needless artifice.

The numbers are embedded in the language.  They are defined by
the theory that calls them forth, and are couched in those terms.

Come up with a theory that defines the Rydberg constant a
different way, and it can be expressed in those terms.

>>> It may be that around about the time these
>>> consistent sets were started to be generated,
[quoted text clipped - 16 lines]
> Whatever version of reality I think I'm in is
> irrelevant to what the external world really is.

It really isn't anything.  You keep impressing your personal
beliefs on what you want to find, and how other people must act.

> I believe that, but it doesn't stop me from trying
> to figure out the true nature of an external world
[quoted text clipped - 6 lines]
> I am wrong. And I completely realize that right
> now, it is highly unlikely I am correct.

Well, so far you are entirely incorrect, wasting your effort in a
search for something you do not yet realize is not available to
mortals, and telling those responsible for CODATA that they made
a mistake.

> But remember, lots of folks thought relativity was
> highly likely to be incorrect before it was proven
> (imo) to be correct.

"They laughed at Bozo the clown too."  Carl Sagan

> Now, you may think I am an egomaniac by making
> such a statement, and I would understand why. But
> what if I'm right?

No chance of that.  Not in this particular "quest".

I was in a similar position to where you are now.  I was just
sure that c was changing with time.  I said many of the same
things, as I was presented with various facts, which were still
sinking in.

>> You are obsessed with inanities.  You have a
>> sharp mind.  Why do you work on dirt with it?
[quoted text clipped - 6 lines]
> even by people I really do respect scientifically
> (like Bilge, etc.)

That was my handle for a while... Village Idiot.

You have intensity.  You have some grasp of science.  I am merely
telling you you are obsessed on the wrong thing.  Once you can
step back and see that, you will be a lot happier.

> For the past several years, I've worked as a
> synthetic aperture radar (SAR) scientist. When
[quoted text clipped - 7 lines]
> same flaws (imo) in the union of the physics and
> statistics in SAR theory that had occurred in QM.

Well, it is a good sign that you are aware that this is your
opnion.

> It has a lot to do with the rather strange
> interpretations of the UP that both of these fields
> maintain, and that I think are incorrect This
> concentrating on these ideas in the past few years
> have given me hope that I may convince people I
> might be correct, so I'm back trying again.

Asperger's syndrome is like this too.

As I have tried to tell you more than once, all of Science is
deterministic.  They simply place the determinism in different
places.  And you still have some very naive expectations of the
way Nature "really" is, about what is "true", how you feel they
should be arranged / handled / expressed.

Let me give you an example.  There have been more than one poster
that has come through here, that felt that we should make c =
300,000 km/sec exactly, and that Science would be well advanced,
and all would be mystically made clear by this change in units.
Its just a number.  Lots of other constants derive from it, and a
step change, just feeds those with other delusions.

Now I say to you, Rydberg's constant is just a number.

> Alas, though, I present much of the same arguments
> I have in the past, and the anti-response is much the
[quoted text clipped - 5 lines]
> presenting a solution to a "problem" that no one thinks
> really exists?

The problem is not where you think it is.  That is what is
gnawing at you.

> Sometimes, though, by presenting the solution to
> some supposed "non problem," others see the
> problem was actually there all along.

You are placing your personal validation in the hands of others.
Why do you do this?

> But I think I'll hold off in saying what I think is the
> solution to the observed-predicted hydrogen Rydberg
> constant "problem." I have a thick hide, but maybe
> not so thick that I can take another barrage of bullets,
> which I know would be shot at me, if not an atomic
> bomb.

No bombs.

> Probably by then, a lot of folks would think the only
> way to get rid of this horrible infestation named "Bell"
> would be to nuke it to death.

You are at least more conversant than most cranks, better read
than the average newbie.  Everybody has their private obsession.
May you find some peace with yours.

> And even from the stinkiest of dirt, sometimes
> beautiful flowers can be grown.

In this case, the dirt is sterile.

David A. Smith
Steve Bell - 25 Apr 2008 18:49 GMT
> Dear Steve Bell:
>
> > Personally, I don't view GR as statistical in any
> > way. To me, it is a completely deterministic theory.
>
> All of science is deteministic.  GR only applies to populations.

Hi David,

I would think that many people would disagree with this. I imagine most QM
folks think their science is fundamentally stochastic.

> >>> This brings up another interesting question. Is
> >>> the external world really statistical,
[quoted text clipped - 21 lines]
> decayed, but the population is well behaved.  It *is*
> deterministic.

Do you believe that indeed, specific ones did decay, and other specific ones
did not? Be careful here, because if you say "yes," to me that means you do
believe that something physically happened in a certain way, even when you
admit you don't know which decayed and which did not. The "butcher's thumb"
was not "on the scal