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Natural Science Forum / Physics / Research / October 2007



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The least action principle as a consequence of Maxent

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jb - 07 Sep 2007 14:14 GMT
I have discovered a simple and amazing result, a surprising
consequence of the maximum entropy principle, and would like to know
if it is true or not. Here it is:

Mathematically, from the set of constraints (p_i reads p with indice
i, sums are over all values of i):
     I = sum (-p_i ln p_i) maximum
     x = sum (p_i * x_i)
     t = sum (p_i * t_i)
one can deduce, using Lagrange multipliers, that:
     L = dI/dt satisfies d°L/d°x = (d/dt)d°L/d°(x_dot)  where d°
means partial differential and x_dot==dx/dt.

L has the property of the Lagrangian in physics. Up to a
multiplicative constant of dimension Action, L is the Lagrangian, I
the action, the Lagrange multiplier of the (generalised) coordinates
are the (generalised) momenta, and the Lagrange multiplier of the time
is the opposite of the Hamiltonian. All Lagrangian mechanics can be
deduced from this set of constraints.

A detailed demonstration can be found at http://hal.archives-ouvertes.fr/hal-00123252/en/

It means that all lagrangian mechanics can be deduced from:
1/ the hypothesis (more natural, I think, that the least action
principle) that all we know is an average path in spacetime
coordinates.
2/ the use of Maxent, which is justified by the repeatability of the
experiment.

Could anyone confirm (or infirm) this fact?
Arnold Neumaier - 08 Sep 2007 01:13 GMT
Jean-Bernard Brissaud wrote:

> I have discovered a simple and amazing result, a surprising
> consequence of the maximum entropy principle, and would like to know
[quoted text clipped - 15 lines]
> is the opposite of the Hamiltonian. All Lagrangian mechanics can be
> deduced from this set of constraints.

A nice observation, which looks correct, though presented somewhat
sloppy. You should keep lambda since the multipliers will also need a
lambda-dependence, and you must integrate over lambda. Also, you need
to take into account boundary conditions in the integral to get the
correct form of the stationary action principle. (You don't prove
minimality of the action, although perhaps you could with more refined
arguments or assumptions. Note that in some applications, the action is
maximized rather than minimized!)

> A detailed demonstration can be found at http://hal.archives-ouvertes.fr/hal-00123252/en/

and arXiv:physics/0701127.

What you call Cauchy-Riemann equations are generally called
Euler-Lagrange equations. Also it is strange that you say after (1)
that you maximize information and after (13) call your principle
the least information principle. You'd check your productions for
consistency internally and with the literature before you make
them public!

Rather than introducing the constant K after the derivation of the
equations, you'd put it into the definition of I. One can give the
entropy arbitrary units without changing anything; this corresponds
choosing an arbitrary basis for the logarithm. (For example, in
computer science, one takes the basis 2 instead of e.) This also
makes your remark on K in Section 3 obsolete. (Anyway, it should
have said raises instead of rests.)

> It means that all lagrangian mechanics can be deduced from:
> 1/ the hypothesis (more natural, I think, that the least action
> principle) that all we know is an average path in spacetime
> coordinates.
> 2/ the use of Maxent, which is justified by the repeatability of the
> experiment.

This is just an opinion, not a fact. Rewriting existing physics
in another form is relevant only if it produces visible results,
such as shorter derivations of consequences, better numerical
methods, new applications, etc.. What you found is a connection
between the two settings, not a more natural foundation.

Regarding the status of the maximum entropy principle as a fundamental
principle of Nature, you may wish to read the strong counterarguments
given in Appendix B of my paper
    A. Neumaier
    On the foundations of thermodynamics
    Manuscript (2007)
    arXiv:0705.3790
You might wish to relate your results to the laws of
thermodynamics as presented there. Your basic equation (2) is just
an expression of the first law of thermodynamics as derived in
Theorem 10.2 of my paper. But I derive the extremal principle
and the first law from assumed Gibbs states, instead of basing it on
the questionable max entropy principle. (If you assume the relation
in your equation before (20) and write S_i for -log p_i, you are
in the setting of my Definition 4.2 for a Gibbs state.) This will
also give the right framework for a quantum version of your result.

There has been previous work relating mechanics and max entropy.
Your work reminds me of
   BR Frieden
   Physics from Fisher Information: A Unification
   Cambridge Univ. Press 1998,
although I don't remember the details. (A nice observation
without further consequences, as in your case, but then inflated
into a series of papers and a book.) A review of the book is in
   Amer J Physics 68 (2000), 1064-1065.
There is also a second edition, now called (more grandiose)
'Science from Fisher Information' which I haven't read.

Arnold Neumaier
Uncle Al - 08 Sep 2007 01:13 GMT
> I have discovered a simple and amazing result, a surprising
> consequence of the maximum entropy principle, and would like to know
[quoted text clipped - 26 lines]
>
> Could anyone confirm (or infirm) this fact?

Oscillating chemical reactions (e.g., Belousov-Zhabotinsky) do not
smoothly go asymptotic to maximum entropy over time.  Energetic
systems far from equilibrium and with positive feedback spotaneously
walk all over the map with strange attractors and repeated
catastrophic transitions - Ilya Prigogine's nonequilibrium
thermodynamics.  

thermodynamics + Bekenstein bound = metric gravitation

Is my preceding paragraph then pertinent to your assertions about
maximizing entropy to trace optimally efficient paths?

Entropy is a weak arrow of time.  The Second Law is strictly
probabilistic.  Angular momentum is an absolute arrow of time, e.g.,
Feynman's sprinkler and fluid diodes with no internal parts.

(Pump water orthogonally into the center of a motion picture film can
and tangentially out its edge and it flows freely.  Pump water
tangentially into the film can's edge with a center exit port and...
no flow.  It is not symmetric to time inversion.)

Signature

Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/lajos.htm#a2

JM Albuquerque - 08 Sep 2007 18:56 GMT
> (Pump water orthogonally into the center of a motion picture film can
> and tangentially out its edge and it flows freely.  Pump water
> tangentially into the film can's edge with a center exit port and...
> no flow.  It is not symmetric to time inversion.)

Based on your picture above, you are wrong if the
can spins.

Starting from a given external potential one can feed
water orthogonally into the center of a motion picture
film can.
If the can is spinning at the right speed water will go
out not tangentially, but orthogonal.

So you can feed the same spinning can externally
and make water come out the other way around.

Otherwise we can build a perpetual motion machine
simply assuming a spinning can.
Uncle Al - 09 Sep 2007 02:25 GMT
> > (Pump water orthogonally into the center of a motion picture film can
> > and tangentially out its edge and it flows freely.  Pump water
[quoted text clipped - 15 lines]
> Otherwise we can build a perpetual motion machine
> simply assuming a spinning can.

If the can spins it is not an inertial frame of reference.  Spin axis
is presumed to be parallel to and concentric with the center feed pipe
orthogonal to the flat plane of the can.

If water enters/exits edge-orthogonal, why spin the can at all?  That
isn't the example.  If there is tangential *entry* and you spin the
can at a *necessary* speed, how do you connect to the tangential port
without leaks?  Its bore is not orthogonal to the edge.  Centripetal
force doesn't time reverse.

The original analysis holds:  entropy is a statistical and weak arrow
of time; angular momentum can be a strong absolute arrow of time.
After all, there is nothing wrong with the Earth spinning the other
way.  The film can fluid diode is something different.

Signature

Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/lajos.htm#a2

a student - 09 Sep 2007 15:15 GMT
> I have discovered a simple and amazing result, a surprising
> consequence of the maximum entropy principle, and would like to know
[quoted text clipped - 26 lines]
>
> Could anyone confirm (or infirm) this fact?

I have had a look at your paper, and have a couple of initial
observations:

1.  The result does not apppear to apply to ALL Lagrangian mechanics,
as the Lagrangian you obtain is always linear in the velocities.  Such
Lagrangians are rare - the only physical one I can think of is for
fields rather than particles - for the Schrodinger equation in fact,
which looks something like
  L(psi, psi*, dpsi/dt, dpsi*/dt) = int dx [ i hbar/m Im{ psi* dpsi/
dt} + V psi psi* ].
So, perhaps the Schrodinger equation can be interpreted as a MaxEnt
evolution over an ensemble of field evolutions.

2.  I am puzzled by a couple of aspects of your derivation.

(a) First, you can only obtain your symmetry conditions
   \partial alpha_k / \partial A_l = \partial alpha_l / \partial A_k
if you assume that (quite reasonably) the average values A_k are all
chosen independently of one other.  However, you then (identifying
your beta with alpha_0 and your t with A_0), assume an explicit
dependence of the A_k on A_0.  How is this consistent with the
derivation of the symmetry conditions?

(b) Second, given that the A_k are all logically independent, you must
be making some sort of added assumption when you restrict them all
depend on A_0 (i.e., t).  That is, you appear to be restricting
consideration to some subset of possible average values, where this
subset is parameterised by A_0=t.  This consideration is put in by
hand, and I'm not sure what the physical meaning is: I guess you are
picking out one of the average values to be a "time" variable, and
asserting that all the other values are to be chosen in a way that is
consistent with MaxEnt for each possible "time" t.  I guess your
result shows that this "simultaneous consistency" restriction
corresponds to Lagrangian evolution for the remaining A_k, with a
Lagrangian linear in dA_k/dt (providing point 2(a) above is not a
problem).
Juan R. - 10 Sep 2007 13:05 GMT
> I have discovered a simple and amazing result, a surprising
> consequence of the maximum entropy principle, and would like to know
[quoted text clipped - 26 lines]
>
> Could anyone confirm (or infirm) this fact?

Yes, overall mechanics can be derived. Quantum mechanics (e.g. the
Schrödinger equation) can be also derived from a corresponding quantum
thermodynamics.

This is not new. A more general expression for a Lagrangian was proven
by Joel Keizer time ago

L(q, {DOT q}) = {{DOT q} - Hq}^T {1/GAMMA} {{DOT q} - Hq}

T, H, and GAMMA defined in [1].

With asociated Lagrange equations

d/ds { {PARTIAL L} / {PARTIAL {DOT q}} } = { {PARTIAL L} / {PARTIAL
{DOT q}} }

determining the extremal, and only the extremal, path.

Those equations are useful for drawing an analogy with mechanics but
of little applicability in real life laboratories because two main
reasons:

1) In laboratory one prefer Hamiltonian mechanics (first order
equations) because of mathematical and computational difficulties with
second order Lagrangian dynamics.

2) Above Lagrangian equations determine the average evolution and not
the observed deviations. For instance, you cannot study Brownian
motion or biochirality using Lagrangian equations because the observed
path in laboratory is *not* the extremal one.

Some remarks about your paper:

i)

{BLOCKQUOTE
 Thermodynamics, on the other hand, can be entirely deduced from the
 maximum entropy principle (Maxent), and introduces a so-called
"arrow of time".
}

MaxEnt methods are not a foundation basis for the whole of
thermodynamics because extremum principles cannot model the
fluctuation spectra in the linear regime, because cannot predict the
average path in the far from equilibrium regime, because does not give
kinetics equations for the non-conserved variables...

Ilya Prigogine (Nobel Prize winner by dissipative structures) showed
that extremum principles do not apply to fully developed non-linear
regimes. Notice that Prigogine developed the main extremum principle
in the linear regime (the theorem cited in the reference 1 you
reference in your own paper).

The equations of motion for a dissipative structure we use in
laboratory do *not* follow from minimizing (or maximizing) some
action. You need other tools like bifurcation theory.

It is well-known that, near a bifurcation point, entropy is not longer
a maximum. The system is unstable at the bifurcation point and MaxEnt
hypotesis breaks down.

About arrows of time, like you know thermodynamics introduces a
fundamental (non-statistical) arrow of time asociated to production of
entropy. However, MaxEnt methods cannot explain that fundamental arrow
just because is formulated over that assumption.

ii)

{BLOCKQUOTE
 Note that in this problem, there are no assumptions about the nature
of the (Ak).
}

No really, you are asumming many things in an implicit way. Between
others:

a)
Ak are differentiable everywhere (you are ruling out bifurcation and
singular points in state space).

b)
I assume that (18) is defined for some t, then you are not considering
memory effects, which are considered in other formulations, e.g.
Truesdell thermomechanics for materials with memory.

c)
Does not the constraint SUM p_i = 1 imply you are ruling out open
systems?

d)
Are not you asumming a classical theory of measurement when doing the
informational interpretation? Also the information function is not
that in quantum thermodynamics

e)
You state are not assuming the Ak to be extensive quantities and that
extensivity is "a thermodynamical concept not necessary for Maxent".
However, the whole method is based in an extensive informational
function

I = - {SUM p_i {LN p_I}}

Probably the most known and studied non-extensive function was Tsallis
[2]

I = {1 - {SUM p_i^q }} / {q - 1}

q parameter measures non-extensivity. In the limit q --> 1 Tsallis
reduces to the classical Gibsian function used in MaxEnt

I = - {SUM p_i {LN p_I}}

iii)

{BLOCKQUOTE
 Maxent as a fundamental physical principle certainly has
 epistemological implications.
}

As stated it is not a fundamental physical principle and has limited
applicability even in the linear regime.

In my opinion, the epistemological implications derived from the
limitations of variational principles are much more interesting
because open a broad scientific vision of Nature and because link with
fundamental epistemological questions like cosmological origins, human
free-will. A discussion of epistemological implications is brilliantly
presented in [3].

[1] J. Chem. Phys. 1975, 63(1), 398.

[2] Journal of Physics A: Math. Gen. 1991, 24, L69.

[3] Prigogine, Ilya. The End of Certainty. Free Press Ed edition, 1997.
jb - 12 Sep 2007 12:27 GMT
On 10 sep, 12:05, "Juan R." <juanrgonzal...@canonicalscience.com>
wrote:

> > I have discovered a simple and amazing result, a surprising
> > consequence of the maximumentropyprinciple, and would like to know
[quoted text clipped - 162 lines]
>
> [3] Prigogine, Ilya. The End of Certainty. Free Press Ed edition, 1997.

Thank you all for these pertinents answers. As I understand it, this
result is already known (and hence true). My faults concern
thermodynamics, not the maths.
M. Neumaier, I agree with you when you say that this needs boundary
conditions. However, the entropy is maximal according to the
probability distribution, and minimal (well, extremal) according to a
variation in the path. No contradiction or paradox here. Note that
this entropy is a priori different from thermodynamical entropy. About
the use of Maxent, the debate is closed for me, your arguments
included (yes, we have to choose the correct variables and
constraints, the variables having an uniform distribution as previous
knowledge). Well, this subject seems almost a religious one, so,
tolerance. I found your paper very interesting, but I don't think we
really talk about the same subject.
Juan R., I'd like to know the generalisation to quantum mechanics. I
can't find the references (my institution didn't pay for) and Joel
Keiser is unknown to google (scholar or not). Could you please give me
a clue. Thanks a lot for your answer, and all the time you spend on
these forums.
Juan R. - 19 Sep 2007 17:31 GMT
> On 10 sep, 12:05, "Juan R." <juanrgonzal...@canonicalscience.com>
> wrote:

> Juan R., I'd like to know the generalisation to quantum mechanics.

You worked at the classical Lagrangian level of mechanics. However a
quantum Lagrangian version is not desired by a number of reasons,
including that quantum Lagrangian Path integral methods can give wrong
S-matrices for important kind of systems. See Weinberg [6] for
detailed discussion about that.

A Hamiltonian approach is more interesting for quantum purposes. There
exists several quantum approaches by different authors. For instance,
in "The Liouville Space Extension of Quantum Mechanics" [1] you can
find one sophisticated and rather complete theory. The senior author
won a Nobel Prize by extension of thermodynamics, and with his group
formulated one of the two main approaches to non-equilibrium
statistical mechanics.

The equation fundamental in [1] is (taking i = 1)

{PARTIAL |RHO_B>> / PARTIAL t} = THETA_B |RHO_B>>

where |RHO_B>> represents the quantum state (a generalization of
quantum wavefunctions) and THETA_B is the evolutor (generalizates the
Hamiltonian operator). The expressions are rather elaborated, e.g.

THETA _B = LAMBDA_B {SUM_v SUM_alpha |F_alpha^(v)>> Z_alpha^(v)
<<TILDE F_alpha^(v)|} {LAMBDA_B}^-1

Where (see [1] for the details):

- LAMBDA_B is a non-unitary (super)operator built over collision and
destruction operators. I avoid to write the math here by lack of time
(see [1] for details).

- Z_alpha^(v) are eigenvalues associated to a novel complex spectral
representation

- The | >> and << | denote a generalization of Dirac bra and kets.

As you know the Schrödinger equation of quantum mechanics is

{PARTIAL |PHI> / PARTIAL t} = H |PHI>

This equation is recovered like a special case of the above
fundamental equation [1]. (See also appendix E: dynamical groups as
approximations of dynamical semigroups on [1]).

In a recent work I. Prigogine writes:

{BLOCKQUOTE
 We see therefore that kinetic theory and thermodynamics are well-
defined
 extensions of classical or quantum dynamics.
}

Whereas the derivation of quantum dinamics from thermodynamics [*] is
interesting for unification issues, the more interesting physics
arises when you consider thermodynamical corrections to Schrödinger.

Then, thanks to non-Schrodinger terms, you can built explicit
'thermomechanical' models for the collapse of wavefunctions. (See
appendix J: collapse of wave functions on [1]).

It is generally thought that collapse is a genuine irreversible
process; it is not so well-known that collapse generates entropy in
agreement with the second law of thermodynamics.

If you are interested, you would contact them [2] for details on
recent Brushles-Austin theory.

I am working a more general theory inspired in early Keizer theory
[4]. The physical ideas behind the derivation of quantum mechanics are
rather close to [1] but technical details are different (e.g. here
Poincaré resonances play no fundamental role). An important aspect is
that theories and equations derived from different groups arise here
as a special kind of this general theory [*].

The basic view is as follow (I avoid most of technical details and do
not use special notation for vectors, operators, and superoperators
because lacking time):

The fundamental equation now is

{PARTIAL RHO / PARTIAL t} = S + D + f

where RHO represents the quantum state. S is streaming term, D
introduces dissipation, and f possible random contributions (e.g. due
to quantum structure of space).

If both f and D terms can be ignored the equation reduces to the
standard Liouville & von-Neumann equation

{PARTIAL RHO / PARTIAL t} = L RHO

where L is the quantum Liouvillian.

If the state of the quantum system can be approximated by a pure state

RHO = |PHI><PHI|

Then the Liouville & von-Neumann reduces to Schrödinger equation

{PARTIAL PHI / PARTIAL t} = H PHI

Note that the Schrödinger equation of quantum mechanics has been here
derived after making three approximations with clear physical meaning:
no random, no dissipation, pure states.

By relaxing the approximations in different ways then you get
different generalizations to Schrödinger quantum mechanics.

For instance, if you maintain the random term f you get a so-called
Ito-Schrödinger equation

{PARTIAL PHI / PARTIAL t} = H PHI + f

If you ignore f but approximate D in the Markovian limit (physically
means no memory effects), second order in potential (usually called
the lambda^2 t aprox.), Abel kernel... then you get a Zubarev NESOM
equation

{PARTIAL RHO / PARTIAL t} = {L RHO} + EPSILON {RHO - {BAR RHO}}

used in MaxEnt-NESOM [5].

Etcetera.

> I can't find the references (my institution didn't pay for) and Joel
> Keiser is unknown to google (scholar or not).

It is Keizer. Their contributions to physics, chemistry, and biology
are listed in both Google engines, SciFinder, and mayor standard
literature resources.

He was a very brilliant scientist (I consider a genious) but
unfortunately got cancer and passed away some few years ago. An
obituary is here [3].

> Could you please give me
> a clue. Thanks a lot for your answer, and all the time you spend on
> these forums.

Due to flaming in sci.physics.relativity both my email is disabled.
Therefore, I am not acessible now.

For October you would be able to get my new academic e-mail. Please
check my blog http://canonicalscience.blogspot.com/ periodically and
contact with me then. I will try to help you if possible.

[1]  Adv. Chem. Phys. 1997, 99, 1. Petrosky, Tomio; Prigogine, Ilya.

[2]  http://order.ph.utexas.edu/Prigogine.htm

[3]  http://hector.ucdavis.edu/pbk/Obituaries/jkeizer.html

[4]  E.g. search in Scholar by Keizer canonical theory.

[5]  http://arxiv.org/abs/cond-mat/9909160

[6]  The Quantum Theory of Fields (Vol. 1). Cambridge University
Press; 2000. Weinberg, Steven.

[*]  As stated by the author there thermodynamics is equated to
certain extension of dynamics. Unfortunately, most of physicists still
think thermodynamics applies only to macroscopic systems at
equilibrium.

Maybe it is better to leave thermodynamics in his usual meaning in
practice, introducing the word "thermomechanics" for a thermal
generalization of mechanics. With mechanics (classical or quantum)
recovered like a special case. Some authors are already using
thermomechanics in this sense.

What do you think?

[**] It seems that a Brushels-Austin like equation

{PARTIAL |RHO_B>> / PARTIAL t} = THETA_B |RHO_B>>

can be derived like a special case from

{PARTIAL RHO / PARTIAL t} = S + D + f

But this is still under active research.
Arnold Neumaier - 28 Sep 2007 11:49 GMT
Juan R. schrieb:

[Moderator's note: Quoted text trimmed. -P.H.]

> Whereas the derivation of quantum dinamics from thermodynamics [*] is
> interesting for unification issues, the more interesting physics
[quoted text clipped - 10 lines]
> If you are interested, you would contact them [2] for details on
> recent Brushles-Austin theory.

Brushles Austin has no useful hits in google. It is also not
mentioned in

> [2]  http://order.ph.utexas.edu/Prigogine.htm

Please give more details. What is it about? A reference?

Arnold Neumaier
Juan R. - 05 Oct 2007 11:57 GMT
On Sep 28, 12:49 pm, Arnold Neumaier <Arnold.Neuma...@univie.ac.at>
wrote:
> Juan R. schrieb:

> > If you are interested, you would contact them [2] for details on
> > recent Brushles-Austin theory.
>
> Brushles Austin has no useful hits in google. It is also not
> mentioned in

Sorry by typo; it is Brussels-Austin.

The Brussels-Austin group is the group was leaded by Prigogine. We
informally call the theory the "Brussels-Austin theory". Still a
Google search will return results. The best way is to follow directly
the authors' literature [2].

> Please give more details. What is it about?

The idea fundamental is that Poincare resonances split models into two
large classes: integrable and non-integrable. See [1, 2, 3] and
previous message for details on that follows.

Non-integrable systems need of an extension of dynamics and that
extension deal with phenomena like irreversibility, dissipation, and
so called non-deterministic chaos.

Examples of non-integrable class (called LPS [*] in the theory) are
thermodynamics systems, measurement apparatus in quantum mechanics,
instable particles (fields)...

Regarding collapse, this theory *dinamically* differentiates simple
quantum systems (following Schrödinger equation) from measurement
apparatus (Schrödinger does not apply). The difference finds in the
spectra.

Spectral decomposition for an usual quantum system (e.g. atom):

H = SUM_j |Phi_j> E_j <Phi_j|

Spectral decomposition for a measurement apparatus:

L = SUM_v SUM_alpha |F_alpha^(v)>> Z_alpha^(v) <<TILDE F_alpha^(v)|

Equation of motion for an usual quantum system (e.g. atom):

{PARTIAL |PHI> / PARTIAL t} = H |PHI>

Equation of motion for a measurement apparatus:

{PARTIAL |RHO_B>> / PARTIAL t} = THETA_B |RHO_B>>

whith

THETA _B = { LAMBDA_B L {LAMBDA_B}^-1 }

This dynamical distinction is a fundamental point you do not find in
other theories dealing with quantum measurement and collapse. For
example, decoherence approaches _a la_ Zurek, or the histories
formalism of Gell-Mann and Hartle are based in _ad hoc_ splitting into
quantum system and measurement apparatus. Therefore, the development
of realistic models may be guided by experience instead pure theory.

Penrose also tries to dinamically explain collapse. Penrose speculates
that quantum gravity effects in 'large' systems collapse wave
functions. He even offers an estimation of size and find a large
enough system would be of order of average molecules. This is right
since we know that average molecules are not completely quantum [**]
but in the border between quantum and classical worlds.

Prigogine and me agree in several fundamental points but both disagree
on the role of Poincare resonances. I do not think Poincare resonances
are fundamental but product in the large limit (LPS). I think a nice
research program would be so find the roots for LPS because that would
solve some weak points on the Brussels-Austin approach.

As stated in a previous message, it seems that a Brussels-Austin like
equation

{PARTIAL RHO_B / PARTIAL t} = THETA_B RHO_B

can be derived like a special case from a Keizer-like one

{PARTIAL RHO / PARTIAL t} = S + D + f

One can formally obtain the equation in the large limit (LPS), with a
Theta superoperator verifying (6.7) in [1]:

THETA _B = { LAMBDA_B L {LAMBDA_B}^-1 } --> L_0

Therefore there exists a clear link between both theories. But this is
still under active research.

> A reference?

In [2] you can see list of recent published references including best-
seller books like _The End of Certainty, Time, Chaos and the New Laws
of Nature_ for general audiences.

In that book Prigogine presents the novel theory in a broad context
(cosmology, evolutionary biology, nonlinear chemistry, geometry and
general relativity) and discusses philosophical implications.

A concise self-contained presentation of the extended quantum
formulation including appendices to specific topics (wave collapse,
Friedrichs model, instable particles, quantum Lorentz gas, anharmonic
lattices...) and further references on detailed models is [1].

Extension of classical mechanics is presented on [3].

> Arnold Neumaier

Due to flaming in sci.physics.relativity my email is disabled.
Therefore, I am not acessible now.

[*]  Large Poincare Systems.

[**] Its electronic structure is, of course, purely quantum but the
nuclear framework is not, any quantum chemist know.

[1]  Adv. Chem. Phys. 1997, 99, 1. Petrosky, Tomio; Prigogine, Ilya.

[2]  http://order.ph.utexas.edu/Prigogine.htm

[3] Cha. Sol. & Fract. 1996, 7(4), 441-497. Petrosky, Tomio;
Prigogine, Ilya.
Arnold Neumaier - 05 Oct 2007 20:41 GMT
[was: The least action principle as a consequence of Maxent]

Juan R. schrieb:
> On Sep 28, 12:49 pm, Arnold Neumaier <Arnold.Neuma...@univie.ac.at>
> wrote:
[quoted text clipped - 3 lines]
> informally call the theory the "Brussels-Austin theory". Still a
> Google search will return results.

One of the Google results (which compared to your references has
the advantage of being online) is

R.C. Bishop
Brussels-Austin Nonequilibrium Statistical Mechanics: Large Poincare
Systems and Rigged Hilbert Space,
http://www.igpp.de/english/tda/pdf/BrusselsAustin.pdf

Does it contain the essence?

> The best way is to follow directly
> the authors' literature [2].

This is a very long list. Surely not all of them are equally relevant.
Which references there gives the key to this theory?

>> Please give more details. What is it about?
>
[quoted text clipped - 34 lines]
>
> THETA _B = { LAMBDA_B L {LAMBDA_B}^-1 }

All this looks to me to be the same, apart from a change in notation.

> This dynamical distinction is a fundamental point you do not find in
> other theories dealing with quantum measurement and collapse.

>> A reference?
>
> In [2] you can see list of recent published references including best-
> seller books like _The End of Certainty, Time, Chaos and the New Laws
> of Nature_ for general audiences.

I am interested in a (recent) survey for experts, not in a
laymen's book. Theory is easier to understand if not enclouded
in philosophy for everyone...

Arnold Neumaier
galathaea - 08 Oct 2007 04:47 GMT
On Oct 5, 12:41 pm, Arnold Neumaier <Arnold.Neuma...@univie.ac.at>
wrote:
> [was: The least action principle as a consequence of Maxent]
>
[quoted text clipped - 18 lines]
>
> Does it contain the essence?

this is a very nice summary

often you will see the "brussels" school
 or "brussels-austin" approach
discussed in fragmentary expositions
tucked in proceedings on foundations of physics
 or on chaos or dissipative structures

they always seemed to have a hard time fitting in

but this paper doesn't go into some of the important issues
regarding the operationalist foundations these approaches require

the issues with time reversibility
 seem to rely on dynamical extensions
 that occur in an operationalist language
and the rigged hilbert space approach

it is interesting that the "brussels school"
 nowadays is still very operationalist
 as exemplified by the work of bob coecke and others
but that the newer formalism
interpreted as a galois adjunction
 from a hilbert space category to a topos interpretation
 is a much more coherent approach
   which many important computational descriptions
   of time irreversibility

-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-
galathaea: prankster, fablist, magician, liar
Juan R. - 11 Oct 2007 20:38 GMT
On Oct 5, 9:41 pm, Arnold Neumaier <Arnold.Neuma...@univie.ac.at>
wrote:
> [was: The least action principle as a consequence of Maxent]
>
[quoted text clipped - 16 lines]
>
> Does it contain the essence?

It contains the essence of LPS and RHS. And discussed the relatinoship
with dissipation and irreversibility. However, it contains not the
essence of the theory. For instance, does not discuss the general
equation of motion or how one derive Pauli, or generalized Puli
equations, does not present the complex spectral decomposition,
neither introduce details of application to systems of physical
interests: gases, Friedrich model, unstable particles, etc.

Whereas, Bishop analizes critical points of the Brussels formalims (a
good point) and cites adittional references and other reviews (another
good point), He apparently fails to understand the basis of the
formalism and motivations.

also Bishop fails to discern basic points like intrinsic and extrinsic
irreversibility (the kaon example is *extrinsic*); difference between
a coarse-grained and a fine-grained approach (contrary to Bishop
comments, the coarse-grained approach is in conflict with the second
law, precisely this was the historical reason for the search of fine-
grained theories avoiding the conflict and letting us the formulation
of a consistent non-equilibrium statistical mechanics.), etc.

> > The best way is to follow directly
> > the authors' literature [2].
>
> This is a very long list. Surely not all of them are equally relevant.
> Which references there gives the key to this theory?

Abstracts usually differentiate reviews from applications to specific
problems.

In some of the listed works, even one does not need to read abstract.
Take for instance the title of paper "Semigroup Representation of the
Vlasov Evolution"

It is clear this is application of the semigroup formalism of the
theory to classical electrodynamics system: the Vlasov equation is a
Boltzman-like equation very popular for modelling plasmas.

I already cited two comprehensive reviews: one for quantum dynamics
and the other for classical dynamics. You would begin from here and
then move to other references in basis to your own preferences and
research agenda.

> > Spectral decomposition for an usual quantum system (e.g. atom):
>
[quoted text clipped - 17 lines]
>
> All this looks to me to be the same, apart from a change in notation.

Nothing more far from reality.

For instance, |PHI> is a vector on a Hilbert space, whereas |RHO_B>>
is a vector in a more general class of space, called the Liouville
space.

Physically, the vector |RHO_B>> describes both pure and mixed states,
whereas its Hilbert counterpart |PHI> only works for pure quantum
states.

On a simple look to the standard spectral decomposition, one can
notice the Hilbert basis symmetry. However, in the novel theory, the
basis (now for the Liouville space) contains the vector <<TILDE
F_alpha^(v)|. See references cited for definition of the TILDE
operation.

>From a physical view, the asymmetry between 'bras' and 'kets' on the
Liouville space is related to decay times of unstable systems for
instance. The description of unstable quantum systems in a Liouville
space is more general than using Gamow vectors for instance.

> Arnold Neumaier

[1]  Adv. Chem. Phys. 1997, 99, 1. Petrosky, Tomio; Prigogine, Ilya.
 
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