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Natural Science Forum / Physics / Research / July 2008



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Q:Negative water pressure electrolysis?

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fasttrack2a@att.net - 05 Jul 2008 17:36 GMT
This was posted on Sci.math but with little response so sorry for cross
posting. Is this the right Usenet group for this question?

Q:Negative water pressure electralosis! Posted: Jul 3, 2008 12:56 PM  on
Sci.math

Negative water pressure (Stretching water).

Were there ever any experiments conducted for extracting hydrogen
through electrolysis from sea water using a negative water pressure
device? If so did it improve the efficiency of producing hydrogen. Also
where would the hydrogen and oxygen go, would it rise to the top? If
possible, would it reduce the negative pressure of the salt water as
more hydrogen and oxygen bonds are broken until the water reaches
atmospheric pressure?

I googled it and found nothing!

Dan
Dirk Bruere at NeoPax - 08 Jul 2008 11:31 GMT
> This was posted on Sci.math but with little response so sorry for cross
> posting. Is this the right Usenet group for this question?
[quoted text clipped - 13 lines]
>
> I googled it and found nothing!

I would have thought that negative water pressure would have lasted
until the first few bubbles of gas re-pressurised it.

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Dirk

http://www.transcendence.me.uk/ - Transcendence UK
Remote Viewing classes in London

Uncle Al - 09 Jul 2008 07:15 GMT
> This was posted on Sci.math but with little response so sorry for cross
> posting. Is this the right Usenet group for this question?
[quoted text clipped - 13 lines]
>
> I googled it and found nothing!

It's a silly thing (scam).  You cannot get the pressure below the
vapor pressure of water.  Reaction rate increases with concentration.
Increasing the size of bubbles for a given mass of gaseous products
blocks electrode area.  You do not electrolyze saline, you electrolyze
aqueous carbonate or hydroxide.  Chloride to chlorine rather than
water to oxygen.  Seawater is loaded with biological crud that fouls
electrodes.

http://www.mazepath.com/uncleal/htoo.htm

Civilization knows what it is doing, Enviro-whiners do not.  Do not
invest against thermodynamics.

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Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/lajos.htm#a2

Chalky - 10 Jul 2008 03:19 GMT
On Jul 5, 5:36 pm, fasttrac...@att.net wrote:
> This was posted on Sci.math but with little response so sorry for cross
> posting. Is this the right Usenet group for this question?
[quoted text clipped - 15 lines]
>
> Dan

Are you sure you don't just mean positive pressure which is less than
atmospheric?

To produce negative pressure you would need something like a very
strong cylinder with plunger at the bottom having >~ a  ton of weight
hanging off it for every square foot of surface area.

First thing to bear in mind is that the boiling point of water drops
as pressure drops, so the water will rapidly boil.

Secondly, from PV=nRT, as pressure drops to zero, volume of resultant
steam expands to infinity, unless its temperature drops to absolute
zero.
fasttrack2a@att.net - 13 Jul 2008 19:53 GMT
> On Jul 5, 5:36 pm, fasttrac...@att.net wrote:
>
[quoted text clipped - 33 lines]
>
> - Show quoted text -

Yes I did mean negative pressure as you explained it above!

By reading yours and other post the water could not be sea water but
fresh water treated with the right ingredients for the most efficient
electrolysis.

There is a point in negative pressure that the volume increases but the
pressure remains the same on a certain plateau, then as the negative
pressure increases byound this plateau the volume begins to increase
again until it reaches the critical point of negative pressure where the
water will become like a water droplet in a vacuum.

See -----  The hydogen bond network.

The second page @ this site gives a good example of this with a graph.

So hypothetically at any point in negative water pressure can
electrolysis be preformed up to but not including the the water droplet
in a vacumn stage? If this is possible then would it be less or more
efficient for electrolysis then water pressure at sea level?

Dan
Chalky - 15 Jul 2008 18:38 GMT
On Jul 13, 7:53 pm, fasttrac...@att.net wrote:

> > On Jul 5, 5:36 pm, fasttrac...@att.net wrote:
>
[quoted text clipped - 49 lines]
>
> The second page @ this site gives a good example of this with a graph.

There is no way to tell which site you mean.

How do you prevent this water from vaporising while still at positive
but low pressure?

It seems to me that this could at best be a temporary effect if you
reduce pressure quickly enough..........hence not exploitable in the
way you envisage.
 
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