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Natural Science Forum / Chemistry / Organic Synthesis / July 2003



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what is freon made of , any idea?

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Tao Zhu - 02 Jul 2003 13:42 GMT
thank you

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Paul J. Franklin(moderator - sci.chem.organic.synthesis)
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Uncle Al - 08 Jul 2003 15:45 GMT
> thank you

Which Freon?  It is a generic term.  Freons in general are
chlorofluorocarbons.

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Ron - 08 Jul 2003 15:51 GMT
> thank you

Uh????????????????
Which one?
It's not a mixture it's a chemical thus.... (IIRC)
Freon RXYZ
X = carbons-1
Y=hydrogens+1
Z=chlorines (unless there a suffix B, where they are bromines)
everything else is fluorine

Thus Freon R22 is
x = 0 thus C=1
y = 2 thus H=1
z = 2 thus Cl =2
makes dichlorodifluoromethane

Freon R13B    = bromotrifluoromethane (a real ozone killer)

Freon R134    = tetrachloroethane

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Ron Jones

Don't repeat history, see unreported near misses in chemical lab/plant
at http://www.crhf.org.uk

.
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Paul J. Franklin(moderator - sci.chem.organic.synthesis)
http://organicworldwide.net/sci.chem.organic.synthesis
Georgia State University <chepjf@panther.gsu.edu>
Atlanta, GA

LOUIS - 10 Jul 2003 19:43 GMT
Ron wrote:

> Tao Zhu wrote:
> > thank you

> Uh????????????????
> Which one?
[quoted text clipped - 4 lines]
> Z=chlorines (unless there a suffix B, where they are bromines)
> everything else is fluorine

> Thus Freon R22 is
> x = 0 thus C=1
> y = 2 thus H=1
> z = 2 thus Cl =2
> makes dichlorodifluoromethane

-Following a good logic formalism it should be Freon R022 otherwise you
may say
x=2, y=2 and/or z=2...

> Freon R13B    = bromotrifluoromethane (a real ozone killer)

-Again Freon R013B would be more convenient!
Also following your explanation it should be
x=0--> 1 carbon
y=1--> 0 hydrogen
z= bromine = 3
the rest is F ===> CFBr3 ---> tribromofluoromethane and not
trifluorobromomethane

> Freon R134    = tetrachloroethane

-Correct... strangely this freon doesn't contain fluorine :-?

PH Z

 [Part 2, Text/HTML  35 lines]
 [Unable to print this part]

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Paul J. Franklin(moderator - sci.chem.organic.synthesis)
http://organicworldwide.net/sci.chem.organic.synthesis
Georgia State University <chepjf@panther.gsu.edu>
Atlanta, GA

Ron - 14 Jul 2003 17:30 GMT
LOUIS wrote:

> Ron wrote:

>> Tao Zhu wrote:

>>> thank you
>
[quoted text clipped - 6 lines]
>> Z=chlorines (unless there a suffix B, where they are bromines)
>> everything else is fluorine

>> Thus Freon R22 is
>> x = 0 thus C=1
>> y = 2 thus H=1
>> z = 2 thus Cl =2
>> makes dichlorodifluoromethane

> -Following a good logic formalism it should be Freon R022 otherwise
> you may say
> x=2, y=2 and/or z=2...

>> Freon R13B    = bromotrifluoromethane (a real ozone killer)

> -Again Freon R013B would be more convenient!
> Also following your explanation it should be
[quoted text clipped - 3 lines]
> the rest is F ===> CFBr3 ---> tribromofluoromethane and not
> trifluorobromomethane

>> Freon R134    = tetrachloroethane

> -Correct... strangely this freon doesn't contain fluorine :-?

> PH Z

I didn't invent the silly system.  What you see is what some bright spark
invented.  If it's a 2 digits you have to assume there is an implicit '0'
(i.e one carbon)
Ooops! can't even use the sytem properly, yes you are right -
"tribromofluoromethane and not trifluorobromomethane" - great refrigerant
(just got rid of a cryostat that used this - was removed before we dumped
it), great ozone killer - someone told me the UK Ministry of Defence were
stockpilling this one - their equipment uses it, and as it's not made any
more, they bought up all the stocks....

Signature

Ron Jones

Don't repeat history, see unreported near misses in chemical lab/plant
at http://www.crhf.org.uk

.
--
Paul J. Franklin(moderator - sci.chem.organic.synthesis)
http://organicworldwide.net/sci.chem.organic.synthesis
Georgia State University <chepjf@panther.gsu.edu>
Atlanta, GA

 
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