Informations about allyl esters

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Chris Petz - 16 Sep 2003 17:24 GMT

Hi Group!

I'm looking for any consolidated information/materials/books about
allyl esters and their properties. It's quiet hard to find something
about it, even in internet ;-)

Please, give me at least a tip, how and where to find it.

Thank you in advance,

regards,

Dorota

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Paul J. Franklin(moderator - sci.chem.organic.synthesis)
http://organicworldwide.net/sci.chem.organic.synthesis
Georgia State University <chepjf@panther.gsu.edu>
Atlanta, GA

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Uncle Al - 17 Sep 2003 15:23 GMT

> Hi Group!
>
[quoted text clipped - 3 lines]
>
> Please, give me at least a tip, how and where to find it.

Allyl esters are free-radical polymerizable resins used in highly
crosslinked systems. Examples are allyl diglycolcarbonate (CR-39, for
eyeglasses, actually diallyl digylcoldicarbonate) and diallyl
phthalates.

http://www.sartomer.com/

They generally need a good kick to get going, like benzoyl peroxide or
peroxydicarbonate inititators. Acrylics and styrenics will initiate
with soft stuff like AIBN or ketone peroxides.

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Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
"Quis custodiet ipsos custodes?" The Net!
--
Paul J. Franklin(moderator - sci.chem.organic.synthesis)
http://organicworldwide.net/sci.chem.organic.synthesis
Georgia State University <chepjf@panther.gsu.edu>
Atlanta, GA

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Muhammar - 17 Sep 2003 15:29 GMT

Greene, Wuts: Protective Groups in Organic Synthesis (Wiley
Interscience Publ.)

The third volume (1999) has a blue cover, is about 5 cm thick and is
full of references and data - not only about the allyl esters. You
will find your info in the chapter "protection for the carboxyl
group", page 369-413

{Maybe the fourth volume is out already, they autors are pretty good
on updating/expanding the book.} Best luck.

> Hi Group!

> I'm looking for any consolidated information/materials/books about
> allyl esters and their properties. It's quiet hard to find something
> about it, even in internet ;-)

> Please, give me at least a tip, how and where to find it.

> Thank you in advance,

> regards,

> Dorota

Signature

Paul J. Franklin(moderator - sci.chem.organic.synthesis)
http://organicworldwide.net/sci.chem.organic.synthesis
Georgia State University <chepjf@panther.gsu.edu>
Atlanta, GA

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Natural Science Forum / Chemistry / Organic Synthesis / September 2003

Informations about allyl esters