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Natural Science Forum / Chemistry / Organic Synthesis / February 2004Oppenauer Oxidation - Other bases?
Aluminium butoxide is given in references for the Oppenauer oxidation - has anyone had any experience of using other bases? Darren.  SignaturePaul J. Franklin(moderator - sci.chem.organic.synthesis) http://organicworldwide.net/sci.chem.organic.synthesis Georgia State University <chepjf@panther.gsu.edu> Atlanta, GA > Aluminium butoxide is given in references for the Oppenauer oxidation - has > anyone had any experience of using other bases? > > Darren. March gives a reference to fluorenone/NaH. There is a relatively recent review in Synthesis 1018(1994) Lancaster catalogue says that zirconium tert-butoxide gives improved yield but I guess thats too expensive Ian SignaturePaul J. Franklin(moderator - sci.chem.organic.synthesis) http://organicworldwide.net/sci.chem.organic.synthesis Georgia State University <chepjf@panther.gsu.edu> Atlanta, GA |
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